| Section 1. Identification | |||
|---|---|---|---|
| Chemical Name | 2,6-dichlorotoluene | CAS No. | 118-69-4 |
| Synonyms | 1,3-dichloro-2-meth-ylbenzene | Chinese Name | 2,6-二氯甲苯 |
| Molecular Formula | C7H6Cl2 | Molecular Weight | 161.1 |
| UN No. | 3082 | Data Source | PubChem (NIH/NLM) |
| GHS Hazard Classification | |
|---|---|
| Signal Word | DANGER |
| Pictograms | GHS05 · Corrosive GHS07 · Irritant GHS08 · Health Hazard GHS09 · Environmental Hazard |
| Hazard Statements | H302H315H318H319H335H411H412H227H361H400H410 |
| Precautionary Statements | P261P264P264+P265P270P271P273P280P301+P317P302+P352P304+P340P305+P351+P338P305+P354+P338P317P319P321P330P332+P317P337+P317P362+P364P391P403+P233P405P501P203P210P318P370+P378P403 |
| Contents | |||
|---|---|---|---|
| Section 2 | Hazards Identification | Section 4 | First-Aid Measures |
| Section 5 | Fire-Fighting Measures | Section 6 | Accidental Release Measures |
| Section 7 | Handling and Storage | Section 8 | Exposure Controls / Personal Protection |
| Section 9 | Physical and Chemical Properties | Section 11 | Toxicological Information |
| Section 12 | Ecological Information | Section 13 | Disposal Considerations |
| Section 14 | Transport Information | ||
This chemical does not meet GHS hazard criteria for 0.9% (1 of 114) of reports.
H302 (36.8%): Harmful if swallowed [Warning Acute toxicity, oral]
H315 (61.4%): Causes skin irritation [Warning Skin corrosion/irritation]
H318 (34.2%): Causes serious eye damage [Danger Serious eye damage/eye irritation]
H319 (54.4%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]
H335 (55.3%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]
H411 (32.5%): Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]
H412 (32.5%): Harmful to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]
P261, P264, P264+P265, P270, P271, P273, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P305+P354+P338, P317, P319, P321, P330, P332+P317, P337+P317, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 114 reports by companies from 12 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Reported as not meeting GHS hazard criteria per 1 of 114 reports by companies.
There are 11 notifications provided by 113 of 114 reports by companies with hazard statement code(s).
Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.
H227: Combustible liquid [Warning Flammable liquids]
H361: Suspected of damaging fertility or the unborn child [Warning Reproductive toxicity]
H400: Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]
H410: Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]
P203, P210, P273, P280, P318, P370+P378, P391, P403, P405, and P501 (click each P-code to see the statement)
H411: Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]
Fresh air, rest.
Rinse and then wash skin with water and soap.
Rinse with plenty of water (remove contact lenses if easily possible).
Rinse mouth.
Use powder, water spray, carbon dioxide.
If material on fire or involved in fire: Do not extinguish fire unless flow can be stopped or safely confined. Use water in flooding quantities as fog. Solid streams of water may spread fire. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible. Use foam, dry chemical, or carbon dioxide. /Chlorotoluenes/
Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Remove vapour with fine water spray.
SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.
If material not on fire and not involved in fire: Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. Build dikes to contain flow as necessary. Use water spray to knock-down vapors. /Chlorotoluenes/
Personnel protection: Avoid breathing vapors. Keep upwind. ... Do not handle broken packages unless wearing appropriate personal protective equipment. Wash away any material which may have contacted the body with copious amounts of water or soap and water. /Chlorotoluenes/
SRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.
Provision to contain effluent from fire extinguishing. Separated from strong bases and strong oxidants. Cool. Well closed. Keep in a well-ventilated room. Store in an area without drain or sewer access.
No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20 °C.
Personnel protection: ... Wear appropriate chemical protective gloves, boots and goggles. /Chlorotoluenes/
NO open flames. Above 82 °C use a closed system and ventilation.
Use ventilation, local exhaust or breathing protection.
Protective gloves.
Wear safety goggles.
Do not eat, drink, or smoke during work.
Liquid; mp = 2.8 deg C; [eChemPortal: SIDSUNEP] Colorless liquid; [MSDSonline]
COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR.
198 °C @ 760 mm Hg
Soluble in chloroform
Insoluble in water.
Solubility in water, g/100ml at 25 °C: (very poor)
1268.6 kg/cu m @ 20 °C
Liquid density = 1.254 g/cu cm at 20 °C
1.28 g/cm³
Relative density of the vapour/air-mixture at 20 °C (air = 1): 1.00
0.35 [mmHg]
Vapor pressure, Pa at 25 °C: 34
Log Kow = 4.29
Index of refraction: 1.5507 @ 20 °C/D
The use of global and substituent physicochemical structure descriptors for quantitative structure-property relationship studies has been evaluated through direct and autocorrelated applications. Partial least squares analysis has been used to predict the partition coefficient for octanol/water, log P, for chlorinated alkylbenzenes. This investigation revealed that various of the physicochemical parameters considered were highly correlated with the partition coefficient and that partial least squares models based on global, direct or autocorrelated substituent parameters all seem to be adequate for prediction of log P, as compared to results obtained experimentally or by means of standard substituent calculation schemes. However, the use of autocorrelation vectors of connectivity, steric and electronic effects may be preferably due to a high degree of explanation of the molecular descriptor variance.
Dielectric constant
Nuclear quadrupole resonance spectroscopy
Optical coefficient
Quadrupole coupling
Refractive index
Other Classes -> Halogenated Monoaromatics
Occupational hepatotoxin - Secondary hepatotoxins: the potential for toxic effect in the occupational setting is based on cases of poisoning by human ingestion or animal experimentation.
A method was developed to analyze rat tissue, fat and blood for some chlorinated compounds found in an extract of soil from an industrial waste site. Extraction with hexane and ethyl ether-hexane (1 + 1) was followed by concentration over steam, and gas chromatographic analysis with an electron capture detector. Volatile compounds were analyzed in a glass column coated with 6% SP-2100 plus 4% OV-ll on Chromosorb W. Semivolatile compounds, chlorinated compounds and pesticides were analyzed in a 70 m glass capillary column coated with 5 OV-101. Phenols were analyzed in a glass column packed with 1% SP-1240 DA on Supelcoport. The most efficient means of separation was to use the same glass column for volatile compounds, a DB-5 fused silica capillary column for semivolatile compounds, pesticides and phenols, and the same 1% SP-1240 DA glass column for separation of beta-BHC and pentachlorophenol. Recoveries ranged from 86.3 + or - 9.1% (mean + or - SD) to 105 + or - 10.4%. Sensitivities for semivolatile chlorinated compounds, pesticides and phenols were 4 ng/g for fat, 1 ng/g for tissue and 0.2 ng/ml for blood. Sensitivities for volatile compounds were 4-fold higher (16, 4 and 0.8, respectively). Sensitivities for dichlorobenzenes and dichlorotoluenes were 8 ng/g for fat, 2 ng/g for tissue and 0.4 ng/ml for blood.
The substance is toxic to aquatic organisms. It is strongly advised not to let the chemical enter into the environment.
2,6-Dichlorotoluene's production and use as a chemical intermediate in the manufacture of dyestuffs and herbicides may result in its release to the environment through various waste streams. If released to the atmosphere, 2,6-dichlorotoluene will exist solely in the vapor phase in the ambient atmosphere based on an estimated vapor pressure of 0.36 mm Hg at 25 °C. Vapor-phase 2,6-dichlorotoluene is degraded in the atmosphere by reaction with photochemically-produced hydroxyl radicals with a half-life of about 12 days. An estimated Koc value of 5,100 indicates that 2,6-dichlorotoluene may be immobile in soil. Volatilization from moist and dry soil surfaces may occur based on an estimated Henry's Law constant of 4.2X10-3 atm-cu m/mole and 2,6-dichlorotoluene's estimated vapor pressure, respectively. Based on limited data, 2,6-dichlorotoluene may be resistant to anaerobic biodegradation. 2,6-Dichlorotoluene, at 1000 uM, was not readily biodegraded in an anoxic soil slurry; 30-35% biodegradation was reached after 150 days. 2,6-Dichlorotoluene should adsorb to suspended matter and sediment in water based on its estimated Koc value. This compound is expected to volatilize from water surfaces given its Henry's Law constant. Estimated half-lives for a model river and model lake are 4 hours and 5 days, respectively, although adsorption to sediment and particulate matter in the water may attenuate this rate. An estimated BCF value of 1,100 indicates that 2,6-dichlorotoluene may bioconcentrate in aquatic organisms.(SRC)
2,6-Dichlorotoluene's production and use as a chemical intermediate in the manufacture of dyestuffs and herbicides(1) may result in its release to the environment through various waste streams(SRC).
TERRESTRIAL FATE: Based on a recommended classification scheme(1), an estimated Koc value of 5,100(SRC), determined from a measured log Kow(2) and a recommended regression-derived equation(3), indicates that 2,6-dichlorotoluene will be immobile in soil(SRC). Volatilization of 2,6-dichlorotoluene may be important from moist soil surfaces(SRC) given an estimated Henry's Law constant of 4.2X10-3 atm-cu m/mole(SRC), using a recommended regression equation(4), and from dry soil surfaces(SRC) based on an estimated vapor pressure of 0.36 mm Hg(SRC), using a fragment constant method(5). Based on limited data, 2,6-dichlorotoluene may be resistant to biodegradation under anaerobic conditions(SRC). 2,6-Dichlorotoluene, at 1000 uM, was not readily biodegraded in an anoxic soil slurry; 30-35% biodegradation was reached after 150 days(6).
AQUATIC FATE: Based on a recommended classification scheme(1), an estimated Koc value of 5,100(SRC), determined from a measured log Kow(2) and a recommended regression-derived equation(1), indicates that 2,6-dichlorotoluene should adsorb to suspended solids and sediment in water(SRC). 2,6-Dichlorotoluene may volatilize from water surfaces based on an estimated Henry's Law constant of 4.2X10-3 atm-cu m/mole(SRC), developed using a fragment constant estimation method(3). Estimated half-lives for a model river and model lake are 4 hours and 5 days, respectively(1,SRC). An estimated BCF value of 1,100(1,SRC), from a measured log Kow(2), suggests that 2,6-dichlorotoluene will bioconcentrate in aquatic organisms(SRC), according to a recommended classification scheme(4). Based on limited data, 2,6-dichlorotoluene may be resistant to biodegradation under anaerobic conditions(SRC). 2,6-Dichlorotoluene, at 1000 uM, was not readily biodegraded in an anoxic soil slurry; 30-35% biodegradation was reached after 150 days(5).
ATMOSPHERIC FATE: According to a model of gas/particle partitioning of semivolatile organic compounds in the atmosphere(1), 2,6-dichlorotoluene, which has an estimated vapor pressure of 0.36 mm Hg at 25 °C(2), will exist solely as a vapor in the ambient atmosphere. Vapor-phase 2,6-dichlorotoluene is degraded in the atmosphere by reaction with photochemically produced hydroxyl radicals(SRC); the half-life for this reaction in air is estimated to be about 12 days(3,SRC).
Bacterial strains isolated from a landfill site previously used for disposal of chlorinated organic wastes were able to utilize 2,6-dichlorotoluene(1). 2,6-Dichlorotoluene, at 1000 uM, was not readily biodegraded in an anoxic soil slurry; 30-35% biodegradation was reached after 150 days(2).
2,6-Dichlorotoluene reacts with photochemically-produced hydroxyl radicals in the atmosphere by addition to the aromatic ring and H-atom abstraction. The rate constant for the vapor-phase reaction of 2,6-dichlorotoluene with photochemically-produced hydroxyl radicals has been estimated as 1.3X10-12 cu cm/molecule-sec at 25 °C(SRC) using a structure estimation method(1,SRC). This corresponds to an atmospheric half-life of about 12 days at an atmospheric concentration of 5X10+5 hydroxyl radicals per cu cm(1,SRC). 2,6-Dichlorotoluene has an absorption band at 274 nm that extends to about 300 nm(2); it is therefore a candidate for direct photolysis by sunlight. No information concerning photolysis rates could be found; however on irradiation with shorter UV light in dry, nitrogen purged methanol, rapid dehalogenation occurs(3).
An estimated BCF value of 1100 was calculated for 2,6-dichlorotoluene(SRC), using a measured log Kow of 4.29(1) and a recommended regression-derived equation(2). According to a recommended classification scheme(3), this BCF value suggests that bioconcentration in aquatic organisms will occur(SRC).
The Koc of 2,6-dichlorotoluene is estimated as approximately 5,100(SRC), using a measured log Kow of 4.29(1) and a regression-derived equation(2,SRC). According to a recommended classification scheme(3), this estimated Koc value suggests that 2,6-dichlorotoluene will be immobile in soil(SRC).
The Henry's Law constant for 2,6-dichlorotoluene is estimated as 4.2X10-3 atm-cu m/mole(SRC) using a fragment constant estimation method(1). This value indicates that 2,6-dichlorotoluene will volatilize from water surfaces(2,SRC). Based on this Henry's Law constant, the volatilization half-life from a model river (1 m deep, flowing 1 m/sec, wind velocity of 3 m/sec) is estimated as approximately 4 hours(2,SRC). The volatilization half-life from a model lake (1 m deep, flowing 0.05 m/sec, wind velocity of 0.5 m/sec) is estimated as approximately 5 days(2,SRC). This rate may be attenuated by adsorption to sediment and particulate matter in the water(SRC). 2,6-Dichlorotoluene's estimated values for vapor pressure, 0.36 mm Hg(3,SRC), and Henry's Law constant(1,SRC) indicate that volatilization from dry and moist soil surfaces may occur(SRC).
2,6-Dichlorotoluene was detected, but not quantified in the Niagara River of the Lake Ontario Basin(1).
In a comprehensive survey of wastewater from 4000 industrial and publicly owned treatment works (POTWS) sponsored by the Effluent Guidelines Division of the USEPA, 2,6-dichlorotoluene was identified in discharges of the following industrial category (frequency of occurrence, median concn in ppb): organic chemicals (14; 26.7), publicly owned treatment works (5; 40.4)(1). The highest effluent concn was 1424 ppb in the paint and ink industry(1).
Exposure to 2,6-dichlorotoluene would be primarily occupational via inhalation and dermal contact. (SRC)
The substance is toxic to aquatic organisms. It is strongly advised not to let the chemical enter into the environment.
2,6-Dichlorotoluene's production and use as a chemical intermediate in the manufacture of dyestuffs and herbicides may result in its release to the environment through various waste streams. If released to the atmosphere, 2,6-dichlorotoluene will exist solely in the vapor phase in the ambient atmosphere based on an estimated vapor pressure of 0.36 mm Hg at 25 °C. Vapor-phase 2,6-dichlorotoluene is degraded in the atmosphere by reaction with photochemically-produced hydroxyl radicals with a half-life of about 12 days. An estimated Koc value of 5,100 indicates that 2,6-dichlorotoluene may be immobile in soil. Volatilization from moist and dry soil surfaces may occur based on an estimated Henry's Law constant of 4.2X10-3 atm-cu m/mole and 2,6-dichlorotoluene's estimated vapor pressure, respectively. Based on limited data, 2,6-dichlorotoluene may be resistant to anaerobic biodegradation. 2,6-Dichlorotoluene, at 1000 uM, was not readily biodegraded in an anoxic soil slurry; 30-35% biodegradation was reached after 150 days. 2,6-Dichlorotoluene should adsorb to suspended matter and sediment in water based on its estimated Koc value. This compound is expected to volatilize from water surfaces given its Henry's Law constant. Estimated half-lives for a model river and model lake are 4 hours and 5 days, respectively, although adsorption to sediment and particulate matter in the water may attenuate this rate. An estimated BCF value of 1,100 indicates that 2,6-dichlorotoluene may bioconcentrate in aquatic organisms.(SRC)
2,6-Dichlorotoluene's production and use as a chemical intermediate in the manufacture of dyestuffs and herbicides(1) may result in its release to the environment through various waste streams(SRC).
TERRESTRIAL FATE: Based on a recommended classification scheme(1), an estimated Koc value of 5,100(SRC), determined from a measured log Kow(2) and a recommended regression-derived equation(3), indicates that 2,6-dichlorotoluene will be immobile in soil(SRC). Volatilization of 2,6-dichlorotoluene may be important from moist soil surfaces(SRC) given an estimated Henry's Law constant of 4.2X10-3 atm-cu m/mole(SRC), using a recommended regression equation(4), and from dry soil surfaces(SRC) based on an estimated vapor pressure of 0.36 mm Hg(SRC), using a fragment constant method(5). Based on limited data, 2,6-dichlorotoluene may be resistant to biodegradation under anaerobic conditions(SRC). 2,6-Dichlorotoluene, at 1000 uM, was not readily biodegraded in an anoxic soil slurry; 30-35% biodegradation was reached after 150 days(6).
AQUATIC FATE: Based on a recommended classification scheme(1), an estimated Koc value of 5,100(SRC), determined from a measured log Kow(2) and a recommended regression-derived equation(1), indicates that 2,6-dichlorotoluene should adsorb to suspended solids and sediment in water(SRC). 2,6-Dichlorotoluene may volatilize from water surfaces based on an estimated Henry's Law constant of 4.2X10-3 atm-cu m/mole(SRC), developed using a fragment constant estimation method(3). Estimated half-lives for a model river and model lake are 4 hours and 5 days, respectively(1,SRC). An estimated BCF value of 1,100(1,SRC), from a measured log Kow(2), suggests that 2,6-dichlorotoluene will bioconcentrate in aquatic organisms(SRC), according to a recommended classification scheme(4). Based on limited data, 2,6-dichlorotoluene may be resistant to biodegradation under anaerobic conditions(SRC). 2,6-Dichlorotoluene, at 1000 uM, was not readily biodegraded in an anoxic soil slurry; 30-35% biodegradation was reached after 150 days(5).
ATMOSPHERIC FATE: According to a model of gas/particle partitioning of semivolatile organic compounds in the atmosphere(1), 2,6-dichlorotoluene, which has an estimated vapor pressure of 0.36 mm Hg at 25 °C(2), will exist solely as a vapor in the ambient atmosphere. Vapor-phase 2,6-dichlorotoluene is degraded in the atmosphere by reaction with photochemically produced hydroxyl radicals(SRC); the half-life for this reaction in air is estimated to be about 12 days(3,SRC).
Bacterial strains isolated from a landfill site previously used for disposal of chlorinated organic wastes were able to utilize 2,6-dichlorotoluene(1). 2,6-Dichlorotoluene, at 1000 uM, was not readily biodegraded in an anoxic soil slurry; 30-35% biodegradation was reached after 150 days(2).
2,6-Dichlorotoluene reacts with photochemically-produced hydroxyl radicals in the atmosphere by addition to the aromatic ring and H-atom abstraction. The rate constant for the vapor-phase reaction of 2,6-dichlorotoluene with photochemically-produced hydroxyl radicals has been estimated as 1.3X10-12 cu cm/molecule-sec at 25 °C(SRC) using a structure estimation method(1,SRC). This corresponds to an atmospheric half-life of about 12 days at an atmospheric concentration of 5X10+5 hydroxyl radicals per cu cm(1,SRC). 2,6-Dichlorotoluene has an absorption band at 274 nm that extends to about 300 nm(2); it is therefore a candidate for direct photolysis by sunlight. No information concerning photolysis rates could be found; however on irradiation with shorter UV light in dry, nitrogen purged methanol, rapid dehalogenation occurs(3).
An estimated BCF value of 1100 was calculated for 2,6-dichlorotoluene(SRC), using a measured log Kow of 4.29(1) and a recommended regression-derived equation(2). According to a recommended classification scheme(3), this BCF value suggests that bioconcentration in aquatic organisms will occur(SRC).
The Koc of 2,6-dichlorotoluene is estimated as approximately 5,100(SRC), using a measured log Kow of 4.29(1) and a regression-derived equation(2,SRC). According to a recommended classification scheme(3), this estimated Koc value suggests that 2,6-dichlorotoluene will be immobile in soil(SRC).
The Henry's Law constant for 2,6-dichlorotoluene is estimated as 4.2X10-3 atm-cu m/mole(SRC) using a fragment constant estimation method(1). This value indicates that 2,6-dichlorotoluene will volatilize from water surfaces(2,SRC). Based on this Henry's Law constant, the volatilization half-life from a model river (1 m deep, flowing 1 m/sec, wind velocity of 3 m/sec) is estimated as approximately 4 hours(2,SRC). The volatilization half-life from a model lake (1 m deep, flowing 0.05 m/sec, wind velocity of 0.5 m/sec) is estimated as approximately 5 days(2,SRC). This rate may be attenuated by adsorption to sediment and particulate matter in the water(SRC). 2,6-Dichlorotoluene's estimated values for vapor pressure, 0.36 mm Hg(3,SRC), and Henry's Law constant(1,SRC) indicate that volatilization from dry and moist soil surfaces may occur(SRC).
2,6-Dichlorotoluene was detected, but not quantified in the Niagara River of the Lake Ontario Basin(1).
In a comprehensive survey of wastewater from 4000 industrial and publicly owned treatment works (POTWS) sponsored by the Effluent Guidelines Division of the USEPA, 2,6-dichlorotoluene was identified in discharges of the following industrial category (frequency of occurrence, median concn in ppb): organic chemicals (14; 26.7), publicly owned treatment works (5; 40.4)(1). The highest effluent concn was 1424 ppb in the paint and ink industry(1).
Exposure to 2,6-dichlorotoluene would be primarily occupational via inhalation and dermal contact. (SRC)
SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.
/GUIDE 129: FLAMMABLE LIQUIDS (POLAR/WATER-MISCIBLE/NOXIOUS)/ Fire or Explosion: HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Those substances designated with "P" may polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. /Chlorotoluenes/
/GUIDE 129: FLAMMABLE LIQUIDS (POLAR/WATER-MISCIBLE/NOXIOUS)/ Health: May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution. /Chlorotoluenes/
/GUIDE 129: FLAMMABLE LIQUIDS (POLAR/WATER-MISCIBLE/NOXIOUS)/ Public Safety: CALL Emergency Response Telephone Number ... . As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering. /Chlorotoluenes/
/GUIDE 129: FLAMMABLE LIQUIDS (POLAR/WATER-MISCIBLE/NOXIOUS)/ Protective Clothing: Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing will only provide limited protection. /Chlorotoluenes/
For more DOT Emergency Guidelines (Complete) data for 2,6-DICHLOROTOLUENE (8 total), please visit the HSDB record page.
UN 2238; Chlorotoluenes
IMO 3.3; Chlorotoluenes
49 131 48; Chlorotoluenes
No person may /transport,/ offer or accept a hazardous material for transportation in commerce unless that person is registered in conformance ... and the hazardous material is properly classed, described, packaged, marked, labeled, and in condition for shipment as required or authorized by ... /the hazardous materials regulations (49 CFR 171-177)./
The International Air Transport Association (IATA) Dangerous Goods Regulations are published by the IATA Dangerous Goods Board pursuant to IATA Resolutions 618 and 619 and constitute a manual of industry carrier regulations to be followed by all IATA Member airlines when transporting hazardous materials.
The International Maritime Dangerous Goods Code lays down basic principles for transporting hazardous chemicals. Detailed recommendations for individual substances and a number of recommendations for good practice are included in the classes dealing with such substances. A general index of technical names has also been compiled. This index should always be consulted when attempting to locate the appropriate procedures to be used when shipping any substance or article.
UN Hazard Class: 9; UN Pack Group: III