| Section 1. Identification | |||
|---|---|---|---|
| Chemical Name | N,N-diethyl-4-nitrosoaniline | CAS No. | 120-22-9 |
| Synonyms | N,N-diethyl-4-nitrosoaniline; 4-nitroso-N,N-diethyl aniline | Chinese Name | 4-亚硝基-N,N-二乙基苯胺 |
| Molecular Formula | C10H14N2O | Molecular Weight | 178.24 |
| UN No. | 3088 | Data Source | PubChem (NIH/NLM) |
| GHS Hazard Classification | |
|---|---|
| Signal Word | DANGER |
| Pictograms | GHS02 · Flammable GHS06 · Acute Toxic |
| Hazard Statements | H228H301H311H331 |
| Precautionary Statements | P210P240P241P261P262P264P270P271P280P301+P316P302+P352P304+P340P316P321P330P361+P364P370+P378P403+P233P405P501 |
| Contents | |||
|---|---|---|---|
| Section 2 | Hazards Identification | Section 4 | First-Aid Measures |
| Section 5 | Fire-Fighting Measures | Section 6 | Accidental Release Measures |
| Section 7 | Handling and Storage | Section 8 | Exposure Controls / Personal Protection |
| Section 9 | Physical and Chemical Properties | Section 10 | Stability and Reactivity |
| Section 14 | Transport Information | ||
This chemical does not meet GHS hazard criteria for 2.3% (1 of 44) of reports.
H228 (11.4%): Flammable solid [Danger Flammable solids]
H301 (97.7%): Toxic if swallowed [Danger Acute toxicity, oral]
H311 (97.7%): Toxic in contact with skin [Danger Acute toxicity, dermal]
H331 (88.6%): Toxic if inhaled [Danger Acute toxicity, inhalation]
P210, P240, P241, P261, P262, P264, P270, P271, P280, P301+P316, P302+P352, P304+P340, P316, P321, P330, P361+P364, P370+P378, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 44 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Reported as not meeting GHS hazard criteria per 1 of 44 reports by companies.
There are 3 notifications provided by 43 of 44 reports by companies with hazard statement code(s).
Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.
Excerpt from ERG Guide 134 [Flammable Solids - Toxic and/or Corrosive]:
Refer to the "General First Aid" section. Specific First Aid: For corrosives, in case of contact, immediately flush skin or eyes with running water for at least 30 minutes. Additional flushing may be required. (ERG, 2024)
Excerpt from ERG Guide 134 [Flammable Solids - Toxic and/or Corrosive]:
SMALL FIRE: Dry chemical, CO2, water spray or alcohol-resistant foam.
LARGE FIRE: Water spray, fog or alcohol-resistant foam. If it can be done safely, move undamaged containers away from the area around the fire. Avoid aiming straight or solid streams directly onto the product. Do not get water inside containers. Dike runoff from fire control for later disposal.
FIRE INVOLVING TANKS, RAIL TANK CARS OR HIGHWAY TANKS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks in direct contact with flames. (ERG, 2024)
Excerpt from ERG Guide 134 [Flammable Solids - Toxic and/or Corrosive]:
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area for at least 25 meters (75 feet) in all directions.
LARGE SPILL: Consider initial downwind evacuation for at least 100 meters (330 feet).
FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024)
Excerpt from ERG Guide 134 [Flammable Solids - Toxic and/or Corrosive]:
ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. Stop leak if you can do it without risk. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Prevent entry into waterways, sewers, basements or confined areas. Use clean, non-sparking tools to collect material and place it into loosely covered plastic containers for later disposal. (ERG, 2024)
Excerpt from ERG Guide 134 [Flammable Solids - Toxic and/or Corrosive]:
Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE. Structural firefighters' protective clothing provides thermal protection but only limited chemical protection. (ERG, 2024)
P-nitrosodiethylaniline is a green solid. Insoluble in water.
Diamagnetic susceptibility
Magnetic susceptibility
Insoluble in water.
Nitro, Nitroso, Nitrate, and Nitrite Compounds, Organic
Amines, Aromatic
A nitrated aromatic amine. Amines are combustible. The combustion of amines yields noxious NOx. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. Aromatic nitro compounds range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. The aromatic nitro compounds may explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water or organic solvents. The explosive tendencies of aromatic nitro compounds are increased by the presence of multiple nitro groups.
Flammable Solid Poison