English Safety Data Sheet Database 中文版 MSDS

sodium oxide

CAS No. 1313-59-3 | PubChem CID 73971
Section 1. Identification
Chemical Namesodium oxide CAS No.1313-59-3
Synonymssodiummonoxide Chinese Name氧化钠
Molecular FormulaNa2O Molecular Weight61.9789
UN No.1825 Data SourcePubChem (NIH/NLM)
GHS Hazard Classification
Signal Word DANGER
Pictograms GHS05 · Corrosive
Hazard Statements H314H318
Precautionary Statements P260P264P264+P265P280P301+P330+P331P302+P361+P354P304+P340P305+P354+P338P316P317P321P363P405P501

Section 2. Hazards Identification

This chemical does not meet GHS hazard criteria for 11.4% (81 of 711) of reports.

H314 (86.9%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

H318 (34.6%): Causes serious eye damage [Danger Serious eye damage/eye irritation]

P260, P264, P264+P265, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 711 reports by companies from 17 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Reported as not meeting GHS hazard criteria per 81 of 711 reports by companies.

There are 16 notifications provided by 630 of 711 reports by companies with hazard statement code(s).

Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Section 4. First-Aid Measures

Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer immediately for medical attention.

Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer immediately for medical attention.

Rinse with plenty of water for several minutes (remove contact lenses if easily possible). Refer immediately for medical attention.

Rinse mouth. Do NOT induce vomiting. Refer immediately for medical attention.

Section 5. Fire-Fighting Measures

NO water. Use dry powder, dry sand.

Section 6. Accidental Release Measures

Personal protection: chemical protection suit including self-contained breathing apparatus. Sweep spilled substance into covered dry, plastic containers. Wash away remainder with plenty of water.

Section 7. Handling and Storage

Separated from strong acids and food and feedstuffs. Dry.

Section 8. Exposure Controls / Personal Protection

0.50 [mg/m3]

5.0 [mg/m3]

50 [mg/m3]

A harmful concentration of airborne particles can be reached quickly when dispersed, especially if powdered.

The substance is corrosive to the eyes, skin and respiratory tract. Corrosive on ingestion. Inhalation of the aerosol may cause lung oedema. Medical observation is indicated.

AVOID ALL CONTACT! PREVENT DISPERSION OF DUST! IN ALL CASES CONSULT A DOCTOR!

Use local exhaust. Use breathing protection.

Protective gloves. Protective clothing.

Wear face shield or eye protection in combination with breathing protection if powder.

Do not eat, drink, or smoke during work.

Section 9. Physical and Chemical Properties

CBI; Large Crystals; Other Solid; Dry Powder; Dry Powder; Other Solid; Liquid; Dry Powder; Large Crystals

WHITE LUMPS OR POWDER.

1275 °C (sublimes)

Solubility in water: reaction

2.3 g/cm³

2.27 @25 °C

>400 °C. This produces sodium peroxide and sodium. Attacks many metals in the presence of water.

dielectric constant

crystal structure

enthalpy

radiation

isothermal section

Gibbs energy

phase equilibrium

positional coordinate

temperature-composition section

space group

enthalpy change

phase diagram

unit cell parameter

ion scattering spectroscopy

melting temperature

heat capacity

thermal capacity

photoemission spectroscopy

transition enthalpy

surface anisotropy

geothermal energy content

concentration

thermal diffusivity

phase transition

vibrational properties

film energy band

band structure

formation entropy

electronic surface structure

X-ray diffraction

interplanar spacing

surface structure

magnetic susceptibility

Section 11. Toxicological Information

Serious by all routes of exposure.

Sore throat. Cough. Burning sensation. Laboured breathing. Shortness of breath.

Redness. Pain. Serious skin burns.

Redness. Pain. Burns.

Sore throat. Burning sensation in the throat and chest. Shock or collapse.

Section 14. Transport Information

Do not transport with food and feedstuffs.

UN Hazard Class: 8; UN Pack Group: II

Source: PubChem CID 73971 (NIH/NLM, public domain). Retrieved from PubChem, a public-domain chemistry database maintained by the U.S. National Library of Medicine. Last updated: 2026-08-02 10:04:31.
Disclaimer: This information is compiled for reference only and does not replace the manufacturer's official Safety Data Sheet. Always consult the supplier's SDS before handling any chemical.