| Section 1. Identification | |||
|---|---|---|---|
| Chemical Name | Barium sulfide | CAS No. | 21109-95-5 |
| Synonyms | barium monosulfide; bariumsulfide | Chinese Name | 硫化钡 |
| Molecular Formula | BaS | Molecular Weight | 169.4 |
| UN No. | 3077 | Data Source | PubChem (NIH/NLM) |
| GHS Hazard Classification | |
|---|---|
| Signal Word | WARNING |
| Pictograms | GHS05 · Corrosive GHS06 · Acute Toxic GHS07 · Irritant GHS08 · Health Hazard GHS09 · Environmental Hazard |
| Hazard Statements | H302H332H400H290H301H314H370H312 |
| Precautionary Statements | P261P264P270P271P273P301+P317P304+P340P317P330P391P501P234P260P280P301+P316P301+P330+P331P302+P361+P354P305+P354+P338P316P321P363P390P405P406P308+P316P302+P352P362+P364 |
| Contents | |||
|---|---|---|---|
| Section 2 | Hazards Identification | Section 8 | Exposure Controls / Personal Protection |
| Section 9 | Physical and Chemical Properties | Section 11 | Toxicological Information |
H302: Harmful if swallowed [Warning Acute toxicity, oral]
H332: Harmful if inhaled [Warning Acute toxicity, inhalation]
H400: Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]
P261, P264, P270, P271, P273, P301+P317, P304+P340, P317, P330, P391, and P501 (click each P-code to see the statement)
H290 (82.7%): May be corrosive to metals [Warning Corrosive to Metals]
H301 (82.7%): Toxic if swallowed [Danger Acute toxicity, oral]
H302 (17.3%): Harmful if swallowed [Warning Acute toxicity, oral]
H314 (82.7%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
H332 (92.3%): Harmful if inhaled [Warning Acute toxicity, inhalation]
H400 (100%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]
P234, P260, P261, P264, P270, P271, P273, P280, P301+P316, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P363, P390, P391, P405, P406, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 52 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.
H370: Causes damage to organs [Danger Specific target organ toxicity, single exposure]
P260, P264, P270, P301+P317, P308+P316, P321, P330, P405, and P501 (click each P-code to see the statement)
H301: Toxic if swallowed [Danger Acute toxicity, oral]
H312: Harmful in contact with skin [Warning Acute toxicity, dermal]
H314: Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
P260, P264, P270, P273, P280, P301+P316, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P362+P364, P363, P391, P405, and P501 (click each P-code to see the statement)
0.5 [mg/m3], as Ba, inhalable fraction (soluble compds)[German Research Foundation (DFG)]
0.5 [mg/m3], as Ba
50.0 [mg/m3], as Ba
Intermediate Oral: 0.2 mg/kg/day (L134)
Chronic Oral: 0.2 mg/kg/day (L134)
Dry Powder
Water-soluble, gray powder; [Hawley] Smells like rotten eggs; Hydrolyzes in water; [MSDSonline]
phonon wavenumber
dielectric constant
crystal structure
enthalpy
isothermal section
Gibbs energy
phase equilibrium
positional coordinate
temperature-composition section
space group
molecular structure
enthalpy change
phase diagram
unit cell parameter
melting temperature
charge transfer coefficient
heat capacity
structural phase transition
crystallographic data
acoustic attenuation
Born effective charge
transition enthalpy
band gap energy
structural transition temperature
mode Grueneisen parameter
phase transition
rotational excitation cross section
elastic stiffness
formation entropy
elastic coefficients
bulk modulus
X-ray diffraction
chemical shift
atomic environment
transition entropy
phonon frequency
formation enthalpy
electric conductivity
Barium is a competitive potassium channel antagonist that blocks the passive efflux of intracellular potassium, resulting in a shift of potassium from extracellular to intracellular compartments. The intracellular translocation of potassium results in a decreased resting membrane potential, making the muscle fibers electrically unexcitable and causing paralysis. Some of these barium's effects may also be due to barium induced neuromuscular blockade and membrane depolarization. (L214)
No indication of carcinogenicity to humans (not listed by IARC).
The health effects of the different barium compounds depend on how well the compound dissolves in water or the stomach contents. At low doses, barium acts as a muscle stimulant, while higher doses affect the nervous system, causing cardiac irregularities, tremors, weakness, anxiety, dyspnea, paralysisand possibly death. Barium may also cause gastrointestinal disturbances, damage the kidneys and cause decreases in body weight. (L214)
Oral (L214) ; inhalation (L214)
Ingesting excess barium may cause vomiting, abdominal cramps, diarrhea, difficulties in breathing, increased or decreased blood pressure, numbness around the face, and muscle weakness. High levels may result in changes in heart rhythm or paralysis and possibly death. (L214)
Nephrotoxin - The chemical is potentially toxic to the kidneys in the occupational setting.
ACGIH Carcinogen - Not Classifiable.
LD50: 375 mg/kg (Oral, Rat) (L275)
Intravenous infusion of potassium often relieves many of the symptoms of barium toxicity. (L214)