m-Fluorotoluene

This chemical does not meet GHS hazard criteria for 44% (37 of 84) of reports.

H225 (56%): Highly Flammable liquid and vapor [Danger Flammable liquids]

H315 (48.8%): Causes skin irritation [Warning Skin corrosion/irritation]

H319 (48.8%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]

H335 (52.4%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 84 reports by companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Reported as not meeting GHS hazard criteria per 37 of 84 reports by companies.

There are 7 notifications provided by 47 of 84 reports by companies with hazard statement code(s).

Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

INHALATION: Move to fresh air. If not breathing, give artificial respiration. if breathing is difficult, give oxygen.

EYES OR SKIN: Flush with running water for at least 15 min.; hold eyelids open if necessary. Remove and isolate contaminated clothing and shoes at the site.

INGESTION: If victim is conscious, have victim drink water or milk. DO NOT INDUCE VOMITING. If victim is UNCONSCIOUS OR HAVING CONVULSIONS, do nothing except keep victim warm. (USCG, 1999)

Fire Extinguishing Agents: Small fires: dry chemical, CO2, water spray or foam; large fires: water spray, fog or foam. (USCG, 1999)

Excerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area for at least 50 meters (150 feet) in all directions.

LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet).

FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024)

Excerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]:

ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor-suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean, non-sparking tools to collect absorbed material.

LARGE SPILL: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapor, but may not prevent ignition in closed spaces. (ERG, 2024)

Wear self-contained positive pressure breathing apparatus and full protective clothing. (USCG, 1999)

3-fluorotoluene appears as a colorless liquid with an aromatic odor. Boiling point 239 °C. Flash point 63 °F. Density 0.991 g / cm3 --- may float or sink in water. (USCG, 1999)

Colorless liquid; [Merck Index] Aromatic odor; [Alfa Aesar MSDS]

240.8 °F at 760 mmHg (USCG, 1999)

-125.9 °F (USCG, 1999)

49 °F (USCG, 1999)

0.9986 at 68 °F (USCG, 1999) - Less dense than water; will float

42.39 mmHg (USCG, 1999)

21.8 [mmHg]

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Other Classes -> Halogenated Monoaromatics

Highly flammable.

Aryl Halides

Highly Flammable

3-FLUOROTOLUENE may be incompatible with strong oxidizing and reducing agents. Also may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. Generates toxic fluoride fumes when burned.

Flammable Liquid