English Safety Data Sheet Database 中文版 MSDS

2-methylhexane

CAS No. 591-76-4 | PubChem CID 11582
Section 1. Identification
Chemical Name2-methylhexane CAS No.591-76-4
Synonymsisoheptane Chinese Name异庚烷
Molecular FormulaC7H16 Molecular Weight100.2
UN No.1206 Data SourcePubChem (NIH/NLM)
GHS Hazard Classification
Signal Word DANGER
Pictograms GHS02 · Flammable GHS07 · Irritant GHS08 · Health Hazard GHS09 · Environmental Hazard
Hazard Statements H225H304H315H336H400H410H335
Precautionary Statements P210P233P240P241P242P243P261P264P271P273P280P301+P316P302+P352P303+P361+P353P304+P340P319P321P331P332+P317P362+P364P370+P378P391P403+P233P403+P235P405P501

Section 2. Hazards Identification

H225: Highly Flammable liquid and vapor [Danger Flammable liquids]

H304: May be fatal if swallowed and enters airways [Danger Aspiration hazard]

H315: Causes skin irritation [Warning Skin corrosion/irritation]

H336: May cause drowsiness or dizziness [Warning Specific target organ toxicity, single exposure; Narcotic effects]

H400: Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]

H410: Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]

P210, P233, P240, P241, P242, P243, P261, P264, P271, P273, P280, P301+P316, P302+P352, P303+P361+P353, P304+P340, P319, P321, P331, P332+P317, P362+P364, P370+P378, P391, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

H225 (51.9%): Highly Flammable liquid and vapor [Danger Flammable liquids]

H304 (100%): May be fatal if swallowed and enters airways [Danger Aspiration hazard]

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]

H335 (10.2%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

H336 (100%): May cause drowsiness or dizziness [Warning Specific target organ toxicity, single exposure; Narcotic effects]

H400 (100%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]

H410 (100%): Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]

Aggregated GHS information provided per 216 reports by companies from 14 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]

H315 (98.6%): Causes skin irritation [Warning Skin corrosion/irritation]

H400 (94.4%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]

Aggregated GHS information provided per 71 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Section 4. First-Aid Measures

Fresh air, rest.

Remove contaminated clothes. Rinse and then wash skin with water and soap.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Rinse mouth. Do NOT induce vomiting.

Section 5. Fire-Fighting Measures

NO water. Use alcohol-resistant foam, powder, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.

Section 6. Accidental Release Measures

Remove all ignition sources. Evacuate danger area! Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT wash away into sewer.

Section 7. Handling and Storage

Fireproof. Separated from strong oxidants.

Section 8. Exposure Controls / Personal Protection

500.0 [ppm]

400.0 [ppm]

400 ppm as TWA; 500 ppm as STEL

No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20 °C.

If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis. The substance may cause effects on the central nervous system at high levels.

The substance defats the skin, which may cause dryness or cracking.

NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. Prevent build-up of electrostatic charges (e.g., by grounding). Do NOT use compressed air for filling, discharging, or handling.

Use ventilation, local exhaust or breathing protection.

Protective gloves.

Wear safety spectacles.

Do not eat, drink, or smoke during work.

Section 9. Physical and Chemical Properties

Colorless liquid; [ICSC]

COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR.

-18 °C c.c.

Solubility in water: none

Relative density (water = 1): 0.68

Relative vapor density (air = 1): 3.4

66.0 [mmHg]

Vapor pressure, kPa at 14.9 °C: 5.3

Boiling point

Chemical diffusion

Critical point

Diamagnetic susceptibility

Dielectric constant

Diffusion

Diffusive flux

Excess enthalpy

Fusion temperature

Heat of solution

Heat of sublimation

Magnetic susceptibility

Melting temperature

Mixing enthalpy

Optical coefficient

Phase diagram

Phase equilibrium

Phase transition

Refractive index

Sound absorption

Sound propagation

Sound velocity

Surface tension

Thermal expansion coefficient

Transition enthalpy

Vapor pressure

Virial coefficient

Viscosity

FCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR

Solvents -> Aliphatics, Saturated (<C12)

Section 11. Toxicological Information

Petroleum distillates are central nervous system depressants and cause pulmonary damage. (A600)

No indication of carcinogenicity to humans (not listed by IARC).

Petroleum distillates are aspiration hazards and may cause pulmonary damage, central nervous system depression, and cardiac effects such as cardiac arrhythmias. They may also affect the blood, immune system, liver, and kidney. (A600, L1297)

The substance can be absorbed into the body by inhalation of its vapour and by ingestion.

Oral (T29) ; inhalation (T29) ; dermal (T29)

Headache. Nausea. Vomiting. Dizziness.

Dry skin.

Further see Inhalation.

Heptane affects the central nervous system and may cause lightheadedness, giddiness, stupor, vertigo, incoordination, loss of appetite, nausea, and unconsciousness. Direct skin contact with heptane may cause pain, burning, and itching. (T29)

Neurotoxin - Acute solvent syndrome

LCLo (rat) = 19,500 ppm/4hr

Treatment is mainly symptomatic and supportive. Gastric lavage, emesis, and the administration of activated charcoal should be avoided, as vomiting increases the risk of aspiration. (A600)

Section 14. Transport Information

Symbol: F, Xn, N; R: 11-38-50/53-65-67; S: (2)-9-16-29-33-60-61-62; Note: C

UN Hazard Class: 3; UN Pack Group: II

Source: PubChem CID 11582 (NIH/NLM, public domain). Retrieved from PubChem, a public-domain chemistry database maintained by the U.S. National Library of Medicine. Last updated: 2026-08-02 09:31:04.
Disclaimer: This information is compiled for reference only and does not replace the manufacturer's official Safety Data Sheet. Always consult the supplier's SDS before handling any chemical.