| Section 1. Identification | |||
|---|---|---|---|
| Chemical Name | 2-methylhexane | CAS No. | 591-76-4 |
| Synonyms | isoheptane | Chinese Name | 异庚烷 |
| Molecular Formula | C7H16 | Molecular Weight | 100.2 |
| UN No. | 1206 | Data Source | PubChem (NIH/NLM) |
| GHS Hazard Classification | |
|---|---|
| Signal Word | DANGER |
| Pictograms | GHS02 · Flammable GHS07 · Irritant GHS08 · Health Hazard GHS09 · Environmental Hazard |
| Hazard Statements | H225H304H315H336H400H410H335 |
| Precautionary Statements | P210P233P240P241P242P243P261P264P271P273P280P301+P316P302+P352P303+P361+P353P304+P340P319P321P331P332+P317P362+P364P370+P378P391P403+P233P403+P235P405P501 |
| Contents | |||
|---|---|---|---|
| Section 2 | Hazards Identification | Section 4 | First-Aid Measures |
| Section 5 | Fire-Fighting Measures | Section 6 | Accidental Release Measures |
| Section 7 | Handling and Storage | Section 8 | Exposure Controls / Personal Protection |
| Section 9 | Physical and Chemical Properties | Section 11 | Toxicological Information |
| Section 14 | Transport Information | ||
H225: Highly Flammable liquid and vapor [Danger Flammable liquids]
H304: May be fatal if swallowed and enters airways [Danger Aspiration hazard]
H315: Causes skin irritation [Warning Skin corrosion/irritation]
H336: May cause drowsiness or dizziness [Warning Specific target organ toxicity, single exposure; Narcotic effects]
H400: Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]
H410: Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]
P210, P233, P240, P241, P242, P243, P261, P264, P271, P273, P280, P301+P316, P302+P352, P303+P361+P353, P304+P340, P319, P321, P331, P332+P317, P362+P364, P370+P378, P391, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)
H225 (51.9%): Highly Flammable liquid and vapor [Danger Flammable liquids]
H304 (100%): May be fatal if swallowed and enters airways [Danger Aspiration hazard]
H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]
H335 (10.2%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]
H336 (100%): May cause drowsiness or dizziness [Warning Specific target organ toxicity, single exposure; Narcotic effects]
H400 (100%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]
H410 (100%): Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]
Aggregated GHS information provided per 216 reports by companies from 14 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.
H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]
H315 (98.6%): Causes skin irritation [Warning Skin corrosion/irritation]
H400 (94.4%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]
Aggregated GHS information provided per 71 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Fresh air, rest.
Remove contaminated clothes. Rinse and then wash skin with water and soap.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Rinse mouth. Do NOT induce vomiting.
NO water. Use alcohol-resistant foam, powder, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.
Remove all ignition sources. Evacuate danger area! Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT wash away into sewer.
Fireproof. Separated from strong oxidants.
500.0 [ppm]
400.0 [ppm]
400 ppm as TWA; 500 ppm as STEL
No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20 °C.
If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis. The substance may cause effects on the central nervous system at high levels.
The substance defats the skin, which may cause dryness or cracking.
NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. Prevent build-up of electrostatic charges (e.g., by grounding). Do NOT use compressed air for filling, discharging, or handling.
Use ventilation, local exhaust or breathing protection.
Protective gloves.
Wear safety spectacles.
Do not eat, drink, or smoke during work.
Colorless liquid; [ICSC]
COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR.
-18 °C c.c.
Solubility in water: none
Relative density (water = 1): 0.68
Relative vapor density (air = 1): 3.4
66.0 [mmHg]
Vapor pressure, kPa at 14.9 °C: 5.3
Boiling point
Chemical diffusion
Critical point
Diamagnetic susceptibility
Dielectric constant
Diffusion
Diffusive flux
Excess enthalpy
Fusion temperature
Heat of solution
Heat of sublimation
Magnetic susceptibility
Melting temperature
Mixing enthalpy
Optical coefficient
Phase diagram
Phase equilibrium
Phase transition
Refractive index
Sound absorption
Sound propagation
Sound velocity
Surface tension
Thermal expansion coefficient
Transition enthalpy
Vapor pressure
Virial coefficient
Viscosity
FCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR
Solvents -> Aliphatics, Saturated (<C12)
Petroleum distillates are central nervous system depressants and cause pulmonary damage. (A600)
No indication of carcinogenicity to humans (not listed by IARC).
Petroleum distillates are aspiration hazards and may cause pulmonary damage, central nervous system depression, and cardiac effects such as cardiac arrhythmias. They may also affect the blood, immune system, liver, and kidney. (A600, L1297)
The substance can be absorbed into the body by inhalation of its vapour and by ingestion.
Oral (T29) ; inhalation (T29) ; dermal (T29)
Headache. Nausea. Vomiting. Dizziness.
Dry skin.
Further see Inhalation.
Heptane affects the central nervous system and may cause lightheadedness, giddiness, stupor, vertigo, incoordination, loss of appetite, nausea, and unconsciousness. Direct skin contact with heptane may cause pain, burning, and itching. (T29)
Neurotoxin - Acute solvent syndrome
LCLo (rat) = 19,500 ppm/4hr
Treatment is mainly symptomatic and supportive. Gastric lavage, emesis, and the administration of activated charcoal should be avoided, as vomiting increases the risk of aspiration. (A600)
Symbol: F, Xn, N; R: 11-38-50/53-65-67; S: (2)-9-16-29-33-60-61-62; Note: C
UN Hazard Class: 3; UN Pack Group: II