English Safety Data Sheet Database 中文版 MSDS

Crotyl chloride

CAS No. 591-97-9 | PubChem CID 11589
Section 1. Identification
Chemical NameCrotyl chloride CAS No.591-97-9
Synonymscrotyl chloride; 1-chloro-2-butene Chinese Name1-氯-2-丁烯
Molecular FormulaC4H7Cl Molecular Weight90.5523
UN No.1993 Data SourcePubChem (NIH/NLM)
GHS Hazard Classification
Signal Word DANGER
Pictograms GHS02 · Flammable GHS05 · Corrosive GHS07 · Irritant
Hazard Statements H225H302H314H315H317H318H332H412
Precautionary Statements P210P233P240P241P242P243P260P261P264P264+P265P270P271P272P273P280P301+P317P301+P330+P331P302+P352P302+P361+P354P303+P361+P353P304+P340P305+P354+P338P316P317P321P330P332+P317P333+P317P362+P364P363P370+P378P403+P235P405P501

Section 2. Hazards Identification

H225 (57.5%): Highly Flammable liquid and vapor [Danger Flammable liquids]

H302 (98.9%): Harmful if swallowed [Warning Acute toxicity, oral]

H314 (55.2%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

H315 (44.8%): Causes skin irritation [Warning Skin corrosion/irritation]

H317 (54%): May cause an allergic skin reaction [Warning Sensitization, Skin]

H318 (46%): Causes serious eye damage [Danger Serious eye damage/eye irritation]

H332 (97.7%): Harmful if inhaled [Warning Acute toxicity, inhalation]

H412 (54%): Harmful to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]

P210, P233, P240, P241, P242, P243, P260, P261, P264, P264+P265, P270, P271, P272, P273, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P330, P332+P317, P333+P317, P362+P364, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 87 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Section 9. Physical and Chemical Properties

(E)- and (Z)-forms are liquids; [Merck Index] Clear colorless liquid; [Sigma-Aldrich MSDS]

69.0 [mmHg]

Molecular structure

Optical coefficient

Refractive index

Rotational excitation cross section

Thermal expansion coefficient

Vibrational mode frequency

Other Classes -> Halogenated Aliphatics, Unsaturated

Flammable agents - 3rd degree

Reactive agents - 1st degree

Section 11. Toxicological Information

Dermatotoxin - Skin burns.

Lacrimator (Lachrymator) - A substance that irritates the eyes and induces the flow of tears.

Toxic Pneumonitis - Inflammation of the lungs induced by inhalation of metal fumes or toxic gases and vapors.

LC50 (rat) = 16,300 mg/m3/4hr

Source: PubChem CID 11589 (NIH/NLM, public domain). Retrieved from PubChem, a public-domain chemistry database maintained by the U.S. National Library of Medicine. Last updated: 2026-08-02 09:49:24.
Disclaimer: This information is compiled for reference only and does not replace the manufacturer's official Safety Data Sheet. Always consult the supplier's SDS before handling any chemical.