English Safety Data Sheet Database 中文版 MSDS

Hexene

CAS No. 592-43-8 | PubChem CID 639661
Section 1. Identification
Chemical NameHexene CAS No.592-43-8
Synonyms2-hexene Chinese Name2-已烯
Molecular FormulaC6H2 Molecular Weight84.1595
UN No.3295 Data SourcePubChem (NIH/NLM)
GHS Hazard Classification
Signal Word DANGER
Pictograms GHS02 · Flammable GHS07 · Irritant GHS08 · Health Hazard
Hazard Statements H225H304H315H319H335
Precautionary Statements P210P233P240P241P242P243P261P264P264+P265P271P280P301+P316P302+P352P303+P361+P353P304+P340P305+P351+P338P319P321P331P332+P317P337+P317P362+P364P370+P378P403+P233P403+P235P405P501

Section 2. Hazards Identification

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]

H304 (65.8%): May be fatal if swallowed and enters airways [Danger Aspiration hazard]

H315 (80.3%): Causes skin irritation [Warning Skin corrosion/irritation]

H319 (80.3%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]

H335 (80.3%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P301+P316, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P331, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 76 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

H304 (100%): May be fatal if swallowed and enters airways [Danger Aspiration hazard]

P210, P233, P240, P241, P242, P243, P280, P301+P316, P303+P361+P353, P331, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 2 reports by companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Section 6. Accidental Release Measures

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Section 9. Physical and Chemical Properties

Liquid; Gas Vapor

Liquid; [IUCLID]

Clear colorless liquid; [MSDSonline]

Colorless liquid with a mild odor; [Alfa Aesar MSDS]

Boiling point: 67.9 °C /2-Hexene (E)/; 68.8 °C /2-Hexene (Z)/; 67.1 °C /3-Hexene (E)/; 66.4 °C /3-Hexene (Z)/

Melting point: -133 °C /2-Hexene (E)/; -141.1 °C /2-Hexene (Z)/; -115.4 °C /3-Hexene (E)/; -137.8 °C /3-Hexene (Z)/

Density: 0.6869 g/cu cm @ 20 °C /2-Hexene (E)/; 0.6772 g/cu cm @ 20 °C /2-Hexene (Z)/; 0.6796 g/cu cm @ 20 °C /3-Hexene (Z)/

173.0 [mmHg]

150.0 [mmHg]

155.0 [mmHg]

Vapor pressure= 173 mm Hg @ 25 °C

Index of refraction: 1.3936 @ 20 °C /2-Hexene (E)/; 1.3979 @ 20 °C /2-Hexene (Z)/; 1.3943 @ 20 °C /3-Hexene (E)/; 1.3947 @ 20 °C /3-Hexene (Z)/

Insoluble in water. Soluble in benzene, ether, ethanol. /2-Hexene (E), 2-Hexene (Z), 3-Hexene (E), 3-Hexene (Z)/

50 mg/l in water @ 25 °C

Boiling point

Diamagnetic susceptibility

Dielectric constant

Excess enthalpy

Fusion temperature

Heat of solution

Heat of sublimation

Magnetic susceptibility

Melting temperature

Mixing enthalpy

Optical coefficient

Phase transition

Refractive index

Thermal expansion coefficient

Transition enthalpy

Vapor pressure

Virial coefficient

Other Classes -> Aliphatics, Unsaturated

Fatty Acyls [FA] -> Hydrocarbons [FA11]

Section 11. Toxicological Information

Neurotoxin - Acute solvent syndrome

LC50 (mice) = 40,000 ppm/2h

Basic Treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary ... Anticipate seizures and treat as necessary ... For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline during transport ... Do not use emetics. For ingestion, rinse mouth and administer 5 mL/kg up to 200 mL of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool. Administer activated charcoal ... Treat frostbite with rapid rewarming techniques ... /Aliphatic hydrocarbons and related compounds/

Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious or in respiratory arrest. Positive-pressure ventilation techniques with a bag-valve-mask device may be beneficial. Monitor cardiac rhythm and treat arrhythmias as necessary ... Start an IV with D5W TKO /SRP: "To keep open", minimal flow rate/. Use lactated Ringer's if signs of hypovolemia are present. Watch for signs of fluid overload. Consider drug therapy for pulmonary edema ... Treat seizures with diazepam (Valium) ... Use proparacaine hydrochloride to assist eye irrigation ... /Aliphatic hydrocarbons and related compounds/

RECENTLY IDENTIFIED COMPONENTS OF COFFEE AROMA- HEXENE /FROM TABLE/

Section 12. Ecological Information

RECENTLY IDENTIFIED COMPONENTS OF COFFEE AROMA- HEXENE /FROM TABLE/

Section 13. Disposal Considerations

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Section 14. Transport Information

/GUIDE 128: FLAMMABLE LIQUIDS (NON-POLAR/WATER-IMMISCIBLE)/ Fire or Explosion: HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Those substances designated with a "P" may polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. Substances may be transported hot. /1-Hexene/

/GUIDE 128: FLAMMABLE LIQUIDS (NON-POLAR/WATER-IMMISCIBLE)/ Health: Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution. /1-Hexene/

/GUIDE 128: FLAMMABLE LIQUIDS (NON-POLAR/WATER-IMMISCIBLE)/ Public Safety: CALL Emergency Response Telephone Number ... . As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering. /1-Hexene/

/GUIDE 128: FLAMMABLE LIQUIDS (NON-POLAR/WATER-IMMISCIBLE)/ Protective Clothing: Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing will only provide limited protection. /1-Hexene/

For more DOT Emergency Guidelines (Complete) data for HEXENE (8 total), please visit the HSDB record page.

No person may /transport,/ offer or accept a hazardous material for transportation in commerce unless that person is registered in conformance ... and the hazardous material is properly classed, described, packaged, marked, labeled, and in condition for shipment as required or authorized by ... /the hazardous materials regulations (49 CFR 171-177)./

The International Maritime Dangerous Goods Code lays down basic principles for transporting hazardous chemicals. Detailed recommendations for individual substances and a number of recommendations for good practice are included in the classes dealing with such substances. A general index of technical names has also been compiled. This index should always be consulted when attempting to locate the appropriate procedures to be used when shipping any substance or article.

Source: PubChem CID 639661 (NIH/NLM, public domain). Retrieved from PubChem, a public-domain chemistry database maintained by the U.S. National Library of Medicine. Last updated: 2026-08-02 09:44:10.
Disclaimer: This information is compiled for reference only and does not replace the manufacturer's official Safety Data Sheet. Always consult the supplier's SDS before handling any chemical.