English Safety Data Sheet Database 中文版 MSDS

1,3-cyclohexadiene

CAS No. 592-57-4 | PubChem CID 11605
Section 1. Identification
Chemical Name1,3-cyclohexadiene CAS No.592-57-4
Synonyms Chinese Name1,3-环己二烯
Molecular FormulaC6H8 Molecular Weight80.13
UN No.3295 Data SourcePubChem (NIH/NLM)
GHS Hazard Classification
Signal Word DANGER
Pictograms GHS02 · Flammable GHS07 · Irritant
Hazard Statements H225H335
Precautionary Statements P210P233P240P241P242P243P261P271P280P303+P361+P353P304+P340P319P370+P378P403+P233P403+P235P405P501

Section 2. Hazards Identification

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]

H335 (14.6%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P210, P233, P240, P241, P242, P243, P261, P271, P280, P303+P361+P353, P304+P340, P319, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 48 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Section 4. First-Aid Measures

Fresh air, rest.

Remove contaminated clothes. Rinse and then wash skin with water and soap.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Do NOT induce vomiting. Refer for medical attention .

Section 5. Fire-Fighting Measures

Use water spray, powder, foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.

Section 6. Accidental Release Measures

Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.

Section 7. Handling and Storage

Fireproof. Separated from strong oxidants. Cool. Keep in the dark. Well closed. Store only if stabilized.

Section 8. Exposure Controls / Personal Protection

No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20 °C.

The substance is irritating to the eyes, skin and respiratory tract.

NO open flames, NO sparks and NO smoking. Above 26 °C use a closed system, ventilation and explosion-proof electrical equipment.

Use ventilation.

Protective gloves.

Wear safety spectacles.

Do not eat, drink, or smoke during work.

Section 9. Physical and Chemical Properties

Colorless liquid; [ICSC] Unpleasant odor; [Alfa Aesar MSDS]

COLOURLESS LIQUID.

26 °C c.c.

Solubility in water: none

Relative density (water = 1): 0.84

Relative vapor density (air = 1): 2.8 (calculated)

97.3 [mmHg]

Other Classes -> Aliphatics, Unsaturated

Section 11. Toxicological Information

The substance can be absorbed into the body by inhalation of its vapour.

Sore throat.

Redness.

LC50 (mouse) = 45,000 mg/m3/2hr

Section 14. Transport Information

Airtight.

UN Hazard Class: 3; UN Pack Group: III

Source: PubChem CID 11605 (NIH/NLM, public domain). Retrieved from PubChem, a public-domain chemistry database maintained by the U.S. National Library of Medicine. Last updated: 2026-08-02 09:07:49.
Disclaimer: This information is compiled for reference only and does not replace the manufacturer's official Safety Data Sheet. Always consult the supplier's SDS before handling any chemical.