2,4,6-trinitroanisole

H201: (Deleted) Explosive; mass explosion hazard [Danger Explosives]

H302: Harmful if swallowed [Warning Acute toxicity, oral]

H312: Harmful in contact with skin [Warning Acute toxicity, dermal]

H332: Harmful if inhaled [Warning Acute toxicity, inhalation]

H411: Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]

P210, P230, P240, P250, P261, P264, P270, P271, P273, P280, P301+P317, P302+P352, P304+P340, P317, P321, P330, P362+P364, P370+P380, P372, P373, P391, P401, and P501 (click each P-code to see the statement)

H201 (100%): (Deleted) Explosive; mass explosion hazard [Danger Explosives]

H302+H312+H332 (100%): Harmful if swallowed, in contact with skin or if inhaled [Warning Acute toxicity, oral; acute toxicity, dermal; acute toxicity, inhalation]

H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]

H312 (100%): Harmful in contact with skin [Warning Acute toxicity, dermal]

H332 (100%): Harmful if inhaled [Warning Acute toxicity, inhalation]

H411 (100%): Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]

Aggregated GHS information provided per 38 reports by companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

P210, P230, P240, P250, P280, P370+P380, P372, P373, P401, and P501 (click each P-code to see the statement)

Excerpt from ERG Guide 112 [Explosives - Division 1.1, 1.2, 1.3 or 1.5]:

Refer to the "General First Aid" section. (ERG, 2024)

Excerpt from ERG Guide 112 [Explosives - Division 1.1, 1.2, 1.3 or 1.5]:

CARGO FIRE: DO NOT fight fire when fire reaches cargo! Cargo may EXPLODE! Stop all traffic and clear the area for at least 1600 meters (1 mile) in all directions and let burn. Do not move cargo or vehicle if cargo has been exposed to heat.

TIRE OR VEHICLE FIRE: Use plenty of water - FLOOD it! If water is not available, use CO2, dry chemical or dirt. If possible, and WITHOUT RISK, use unmanned master stream devices or monitor nozzles from maximum distance to prevent fire from spreading to cargo area. Pay special attention to tire fires as re-ignition may occur. Stand by, at a safe distance, with extinguisher ready for possible re-ignition. (ERG, 2024)

Excerpt from ERG Guide 112 [Explosives - Division 1.1, 1.2, 1.3 or 1.5]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area immediately for at least 500 meters (1/3 mile) in all directions.

LARGE SPILL: Consider initial evacuation for 800 meters (1/2 mile) in all directions.

FIRE: If rail car or trailer is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, initiate evacuation including emergency responders for 1600 meters (1 mile) in all directions. (ERG, 2024)

SRP: Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality; potential migration in air, soil or water; effects on animal, aquatic and plant life; and conformance with environmental and public health regulations. If it is possible or reasonable use an alternative chemical product with less inherent propensity for occupational harm/injury/toxicity or environmental contamination.

Excerpt from ERG Guide 112 [Explosives - Division 1.1, 1.2, 1.3 or 1.5]:

ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. DO NOT OPERATE RADIO TRANSMITTERS WITHIN 100 METERS (330 FEET) OF ELECTRIC DETONATORS. DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST. (ERG, 2024)

Excerpt from ERG Guide 112 [Explosives - Division 1.1, 1.2, 1.3 or 1.5]:

Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing provides thermal protection but only limited chemical protection. (ERG, 2024)

Trinitroanisole appears as a crystalline structure. Highly toxic. May explode under exposure to intense heat or fire. Primary hazard is blast of an instantaneous explosion, not flying projectiles or fragments.

Crystals

Needles (from dilute methanol)

Yellow crystals

In water, 200 mg/L at 15 °C, 1368 mg/L at 50 °C

Very soluble in ethanol, chloroform, benzene; soluble in ether

1.408 at 20/4 °C

5.5X10-6 mm Hg at 25 deg (extrapolated from measurements at higher temperatures in the solid phase via Antoine equation)

When heated to decomposition it emits toxic vapors of NOx.

Does not attack metals provided it is protected from moisture.

91.9 kJ/mol (342-363 K)

Explodes by heat or shock

Henry's Law constant = 8.8X10-9 atm-cu m/mole at 25 °C (estimated from vapor pressure and water solubility)

15N nuclear magnetic resonance spectrum

Boiling point

Chemical shift

Heat of sublimation

Spin-spin coupling constant

Vapor pressure

Viscosity

Trinitroanisole is insoluble in water

Nitro, Nitroso, Nitrate, and Nitrite Compounds, Organic

Explosive

Strong Oxidizing Agent

TRINITROANISOLE is one of the least sensitive explosives. It is quite toxic to humans and therefore hasn't been used in general as an explosive.

IDENTIFICATION AND USE: Trinitroanisole is an explosive with a detonation velocity of 7200 meters per second. HUMAN STUDIES: There are no data available. ANIMAL STUDIES: It was found mutagenic in Salmonella/mammalian microsome test. The mutagenic activity did not require metabolic activation, but was largely dependent on the presence of an intact nitroreductase capability in the test bacteria. Reduced metabolites, possibly hydroxylamines, may be the proximal mutagenic intermediates.

/SRP:/ Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. obtain medical attention. /Explosives/

/SRP:/ Basic treatment: Establish a patent airway (oropharyngeal or nasopharyngeal airway, if needed). Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary ... . Monitor for shock and treat if necessary ... . Anticipate seizures and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with 0.9% saline (NS) during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 mL/kg up to 200 mL of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool ... . /Explosives/

/SRP:/ Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious, has severe pulmonary edema, or is in severe respiratory distress. Positive-pressure ventilation techniques with a bag valve mask device may be beneficial. Consider drug therapy for pulmonary edema ... . Monitor cardiac rhythm and treat arrhythmias as necessary ... . Start IV administration of D5W /SRP: "To keep open", minimal flow rate/. Use 0.9% saline (NS) or lactated Ringer's (LR) if signs of hypovolemia are present. For hypotension with signs of hypovolemia, administer fluid cautiously. Watch for signs of fluid overload ... . Treat seizures with diazepam (Valium) or lorazepam (Ativan) ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Explosives/

/SRP:/ Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR if necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Aromatic hydrocarbons and related compounds/

For more Antidote and Emergency Treatment (Complete) data for Trinitroanisole (9 total), please visit the HSDB record page.

/GENOTOXICITY/ A number of nitroaromatic explosives and related compounds were examined for mutagenic activity with the Salmonella/mammalian microsome test. Of 11 nitroaromatics (1,3,6,8-tetranitronaphthalene, 2,3,5-trinitronaphthalene, 2,4,6-trinitro-m-toluidine, 2,4,6-trinitroanisole, 2,3-dinitrotoluene, 2,6-dinitrotoluene, 2,4,6-trinitrotoluene, 2,4-dinitrotoluene, 2,2,4,4,6,6-hexanitrodiphenylamine, 2,4,6-trinitrophenol, 2,4,6-trinitroresorcinol) tested, 9 were mutagenic, including 2,4,6-trinitrotoluene, the most widely produced military explosive. All the nitroaromatics, except 2,4,6-trinitrophenol and 2,3,5-trinitroresorcinol, were at least an order of magnitude more mutagenic than the 3 dinitrotoluene (DNT) isomers. The most active compound was 2,3,5-trinitronaphthalene, which was more mutagenic than DNT isomers. These compounds induced predominantly frameshift mutations. The mutagenic activity did not require S9 activation, but was largely dependent on the presence of an intact nitroreductase capability in the test bacteria. Reduced metabolites, possibly hydroxylamines, may be the proximal mutagenic intermediates.

Trinitroanisole's production and use in explosive compositions may result in its release to the environment through various waste streams. If released to air, a vapor pressure of 5.5X10-6 mm Hg at 25 °C indicates trinitroanisole will exist in both the vapor and particulate phases in the atmosphere. Vapor-phase trinitroanisole will be degraded in the atmosphere by reaction with photochemically-produced hydroxyl radicals; the half-life for this reaction in air is estimated to be 19 days. Particulate-phase trinitroanisole will be removed from the atmosphere by wet and dry deposition. Trinitroanisole absorbs at wavelengths >290 nm and, therefore, may be susceptible to direct photolysis by sunlight. If released to soil, trinitroanisole is expected to have low to no mobility based upon a an estimated Koc of 1120. Volatilization from moist soil surfaces is not expected to be an important fate process based upon an estimated Henry's Law constant of 8.8X10-9 atm-cu m/mole. Trinitroanisole is not expected to volatilize from dry soil surfaces based upon its vapor pressure. Direct photolysis may occur on surfaces exposed to sunlight. Biodegradation data in soil or water were not available. If released into water, trinitroanisole is not expected to adsorb to suspended solids and sediment based upon the estimated Koc. Volatilization from water surfaces is not expected to be an important fate process based upon this compound's estimated Henry's Law constant. An estimated BCF of 5 suggests bioconcentration in aquatic organisms is low. Hydrolysis is not expected to be an important environmental fate process since this compound lacks functional groups that hydrolyze under environmental conditions (pH 5 to 9). Occupational exposure to trinitroanisole may occur through inhalation and dermal contact with this compound at workplaces where trinitroanisole is produced or used. Through its uses in explosive compositions, the general population may be exposed to trinitroanisole via inhalation of ambient air and dermal contact with explosive products containing trinitroanisole. (SRC)

Trinitroanisole's production and use in explosive compositions(1) may result in its release to the environment through various waste streams(SRC).

TERRESTRIAL FATE: Based on a classification scheme(1), an estimated Koc value of 1120(SRC), determined from a structure estimation method(2), indicates that trinitroanisole is expected to have low mobility in soil(SRC). Volatilization of trinitroanisole from moist soil surfaces is not expected to be an important fate process(SRC) given an estimated Henry's Law constant of 8.8X10-9 atm-cu m/mole(SRC), derived from its vapor pressure, 5.5X10-6 mm Hg(3), and water solubility, 200 mg/L(4). Trinitroanisole is not expected to volatilize from dry soil surfaces(SRC) based upon its vapor pressure. Trinitroanisole absorbs at wavelengths >290 nm(5) and, therefore, may be susceptible to direct photolysis on surfaces exposed to sunlight(SRC). Biodegradation data in soil were not available(SRC, 2017).

AQUATIC FATE: Based on a classification scheme(1), an estimated Koc value of 1120(SRC), determined from a structure estimation method(2), indicates that trinitroanisole is expected to adsorb to suspended solids and sediment(SRC). Volatilization from water surfaces is not expected(3) based upon an estimated Henry's Law constant of 8.8X10-9 atm-cu m/mole(SRC), derived from its vapor pressure, 5.5X10-6 mm Hg(4), and water solubility, 200 mg/L(5). According to a classification scheme(6), an estimated BCF of 5(SRC), from an estimated log Kow of 1.53(2) and a regression-derived equation(2), suggests the potential for bioconcentration in aquatic organisms is low(SRC). Trinitroanisole absorbs at wavelengths >290 nm(7) and, therefore, may be susceptible to direct photolysis in waters exposed to sunlight(SRC). Trinitroanisole is not expected to undergo hydrolysis in the environment due to the lack of functional groups that hydrolyze under environmental conditions(3). Biodegradation data in water were not available(SRC, 2017).

ATMOSPHERIC FATE: According to a model of gas/particle partitioning of semivolatile organic compounds in the atmosphere(1), trinitroanisole, which has a vapor pressure of 5.5X10-6 mm Hg at 25 °C(2), will exist in both the vapor and particulate phases in the ambient atmosphere. Vapor-phase trinitroanisole is degraded in the atmosphere by reaction with photochemically-produced hydroxyl radicals(SRC); the half-life for this reaction in air is estimated to be 19 days(SRC), calculated from its rate constant of 8.3X10-13 cu cm/molecule-sec at 25 °C(SRC) that was derived using a structure estimation method(3). Particulate-phase trinitroanisole may be removed from the air by wet and dry deposition(SRC). Trinitroanisole absorbs at wavelengths >290 nm(4) and, therefore, may be susceptible to direct photolysis by sunlight(SRC).

The rate constant for the vapor-phase reaction of trinitroanisole with photochemically-produced hydroxyl radicals has been estimated as 8.3X10-13 cu cm/molecule-sec at 25 °C(SRC) using a structure estimation method(1). This corresponds to an atmospheric half-life of about 19 days at an atmospheric concentration of 5X10+5 hydroxyl radicals per cu cm(1). Trinitroanisole is not expected to undergo hydrolysis in the environment due to the lack of functional groups that hydrolyze under environmental conditions(2). Trinitroanisole absorbs at wavelengths >290 nm(3) and, therefore, may be susceptible to direct photolysis by sunlight(SRC). The structurally similar compounds 2,4,6-trinitrophenol (picric acid) and 2,4,6-trinitrotoluene (TNT) have been shown to directly photolysis in natural waters and distilled water when exposed to solar irradiation(4,5); photolysis half-lives for trinitrotoluene ranged from 10 minutes to 1.3 hours in natural waters and 11.3 hours in distilled water(4).

An estimated BCF of 5 was calculated in fish for trinitroanisole(SRC), using an estimated log Kow of 1.53(1) and a regression-derived equation(1). According to a classification scheme(2), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC).

Using a structure estimation method based on molecular connectivity indices(1), the Koc of trinitroanisole can be estimated to be 1120. According to a classification scheme(2), this estimated Koc value suggests that trinitroanisole is expected to have low mobility in soil.

The Henry's Law constant for trinitroanisole is estimated as 8.8X10-9 atm-cu m/mole(SRC) derived from its vapor pressure, 5.5X10-6 mm Hg(1), and water solubility, 200 mg/L(2). This Henry's Law constant indicates that trinitroanisole is expected to be essentially nonvolatile from water surfaces(3). Trinitroanisole's estimated Henry's Law constant indicates that volatilization from moist soil surfaces is not expected to occur(SRC). Trinitroanisole is not expected to volatilize from dry soil surfaces(SRC) based upon its vapor pressure.

Occupational exposure to trinitroanisole may occur through inhalation and dermal contact with this compound at workplaces where trinitroanisole is produced or used(SRC). Through its uses in explosive compositions(1), the general population may be exposed to trinitroanisole via inhalation of ambient air and dermal contact with explosive products containing trinitroanisole(SRC).

Trinitroanisole's production and use in explosive compositions may result in its release to the environment through various waste streams. If released to air, a vapor pressure of 5.5X10-6 mm Hg at 25 °C indicates trinitroanisole will exist in both the vapor and particulate phases in the atmosphere. Vapor-phase trinitroanisole will be degraded in the atmosphere by reaction with photochemically-produced hydroxyl radicals; the half-life for this reaction in air is estimated to be 19 days. Particulate-phase trinitroanisole will be removed from the atmosphere by wet and dry deposition. Trinitroanisole absorbs at wavelengths >290 nm and, therefore, may be susceptible to direct photolysis by sunlight. If released to soil, trinitroanisole is expected to have low to no mobility based upon a an estimated Koc of 1120. Volatilization from moist soil surfaces is not expected to be an important fate process based upon an estimated Henry's Law constant of 8.8X10-9 atm-cu m/mole. Trinitroanisole is not expected to volatilize from dry soil surfaces based upon its vapor pressure. Direct photolysis may occur on surfaces exposed to sunlight. Biodegradation data in soil or water were not available. If released into water, trinitroanisole is not expected to adsorb to suspended solids and sediment based upon the estimated Koc. Volatilization from water surfaces is not expected to be an important fate process based upon this compound's estimated Henry's Law constant. An estimated BCF of 5 suggests bioconcentration in aquatic organisms is low. Hydrolysis is not expected to be an important environmental fate process since this compound lacks functional groups that hydrolyze under environmental conditions (pH 5 to 9). Occupational exposure to trinitroanisole may occur through inhalation and dermal contact with this compound at workplaces where trinitroanisole is produced or used. Through its uses in explosive compositions, the general population may be exposed to trinitroanisole via inhalation of ambient air and dermal contact with explosive products containing trinitroanisole. (SRC)

Trinitroanisole's production and use in explosive compositions(1) may result in its release to the environment through various waste streams(SRC).

TERRESTRIAL FATE: Based on a classification scheme(1), an estimated Koc value of 1120(SRC), determined from a structure estimation method(2), indicates that trinitroanisole is expected to have low mobility in soil(SRC). Volatilization of trinitroanisole from moist soil surfaces is not expected to be an important fate process(SRC) given an estimated Henry's Law constant of 8.8X10-9 atm-cu m/mole(SRC), derived from its vapor pressure, 5.5X10-6 mm Hg(3), and water solubility, 200 mg/L(4). Trinitroanisole is not expected to volatilize from dry soil surfaces(SRC) based upon its vapor pressure. Trinitroanisole absorbs at wavelengths >290 nm(5) and, therefore, may be susceptible to direct photolysis on surfaces exposed to sunlight(SRC). Biodegradation data in soil were not available(SRC, 2017).

AQUATIC FATE: Based on a classification scheme(1), an estimated Koc value of 1120(SRC), determined from a structure estimation method(2), indicates that trinitroanisole is expected to adsorb to suspended solids and sediment(SRC). Volatilization from water surfaces is not expected(3) based upon an estimated Henry's Law constant of 8.8X10-9 atm-cu m/mole(SRC), derived from its vapor pressure, 5.5X10-6 mm Hg(4), and water solubility, 200 mg/L(5). According to a classification scheme(6), an estimated BCF of 5(SRC), from an estimated log Kow of 1.53(2) and a regression-derived equation(2), suggests the potential for bioconcentration in aquatic organisms is low(SRC). Trinitroanisole absorbs at wavelengths >290 nm(7) and, therefore, may be susceptible to direct photolysis in waters exposed to sunlight(SRC). Trinitroanisole is not expected to undergo hydrolysis in the environment due to the lack of functional groups that hydrolyze under environmental conditions(3). Biodegradation data in water were not available(SRC, 2017).

ATMOSPHERIC FATE: According to a model of gas/particle partitioning of semivolatile organic compounds in the atmosphere(1), trinitroanisole, which has a vapor pressure of 5.5X10-6 mm Hg at 25 °C(2), will exist in both the vapor and particulate phases in the ambient atmosphere. Vapor-phase trinitroanisole is degraded in the atmosphere by reaction with photochemically-produced hydroxyl radicals(SRC); the half-life for this reaction in air is estimated to be 19 days(SRC), calculated from its rate constant of 8.3X10-13 cu cm/molecule-sec at 25 °C(SRC) that was derived using a structure estimation method(3). Particulate-phase trinitroanisole may be removed from the air by wet and dry deposition(SRC). Trinitroanisole absorbs at wavelengths >290 nm(4) and, therefore, may be susceptible to direct photolysis by sunlight(SRC).

The rate constant for the vapor-phase reaction of trinitroanisole with photochemically-produced hydroxyl radicals has been estimated as 8.3X10-13 cu cm/molecule-sec at 25 °C(SRC) using a structure estimation method(1). This corresponds to an atmospheric half-life of about 19 days at an atmospheric concentration of 5X10+5 hydroxyl radicals per cu cm(1). Trinitroanisole is not expected to undergo hydrolysis in the environment due to the lack of functional groups that hydrolyze under environmental conditions(2). Trinitroanisole absorbs at wavelengths >290 nm(3) and, therefore, may be susceptible to direct photolysis by sunlight(SRC). The structurally similar compounds 2,4,6-trinitrophenol (picric acid) and 2,4,6-trinitrotoluene (TNT) have been shown to directly photolysis in natural waters and distilled water when exposed to solar irradiation(4,5); photolysis half-lives for trinitrotoluene ranged from 10 minutes to 1.3 hours in natural waters and 11.3 hours in distilled water(4).

An estimated BCF of 5 was calculated in fish for trinitroanisole(SRC), using an estimated log Kow of 1.53(1) and a regression-derived equation(1). According to a classification scheme(2), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC).

Using a structure estimation method based on molecular connectivity indices(1), the Koc of trinitroanisole can be estimated to be 1120. According to a classification scheme(2), this estimated Koc value suggests that trinitroanisole is expected to have low mobility in soil.

The Henry's Law constant for trinitroanisole is estimated as 8.8X10-9 atm-cu m/mole(SRC) derived from its vapor pressure, 5.5X10-6 mm Hg(1), and water solubility, 200 mg/L(2). This Henry's Law constant indicates that trinitroanisole is expected to be essentially nonvolatile from water surfaces(3). Trinitroanisole's estimated Henry's Law constant indicates that volatilization from moist soil surfaces is not expected to occur(SRC). Trinitroanisole is not expected to volatilize from dry soil surfaces(SRC) based upon its vapor pressure.

Occupational exposure to trinitroanisole may occur through inhalation and dermal contact with this compound at workplaces where trinitroanisole is produced or used(SRC). Through its uses in explosive compositions(1), the general population may be exposed to trinitroanisole via inhalation of ambient air and dermal contact with explosive products containing trinitroanisole(SRC).

SRP: Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality; potential migration in air, soil or water; effects on animal, aquatic and plant life; and conformance with environmental and public health regulations. If it is possible or reasonable use an alternative chemical product with less inherent propensity for occupational harm/injury/toxicity or environmental contamination.

UN 0213; Trinitroanisole

IMO 1.1D; Trinitroanisole

No person may /transport,/ offer or accept a hazardous material for transportation in commerce unless that person is registered in conformance ... and the hazardous material is properly classed, described, packaged, marked, labeled, and in condition for shipment as required or authorized by ... /the hazardous materials regulations (49 CFR 171-177)./

The International Air Transport Association (IATA) Dangerous Goods Regulations are published by the IATA Dangerous Goods Board pursuant to IATA Resolutions 618 and 619 and constitute a manual of industry carrier regulations to be followed by all IATA Member airlines when transporting hazardous materials. Trinitroanisole is included on the dangerous goods list.

The International Maritime Dangerous Goods Code lays down basic principles for transporting hazardous chemicals. Detailed recommendations for individual substances and a number of recommendations for good practice are included in the classes dealing with such substances. A general index of technical names has also been compiled. This index should always be consulted when attempting to locate the appropriate procedures to be used when shipping any substance or article. Trinitroanisole is included on the dangerous goods list.

Explosive 1.1D