English Safety Data Sheet Database 中文版 MSDS

Methyl Crotonate

CAS No. 623-43-8 | PubChem CID 638132
Section 1. Identification
Chemical NameMethyl Crotonate CAS No.623-43-8
Synonymsmethylcrotonate Chinese Name2-丁烯酸甲酯
Molecular FormulaC5H8O2 Molecular Weight100.1158
UN No.3272 Data SourcePubChem (NIH/NLM)
GHS Hazard Classification
Signal Word DANGER
Pictograms GHS02 · Flammable GHS05 · Corrosive GHS07 · Irritant
Hazard Statements H225H315H318H319H335
Precautionary Statements P210P233P240P241P242P243P261P264P264+P265P271P280P302+P352P303+P361+P353P304+P340P305+P351+P338P305+P354+P338P317P319P321P332+P317P337+P317P362+P364P370+P378P403+P233P403+P235P405P501

Section 2. Hazards Identification

H225 (99.4%): Highly Flammable liquid and vapor [Danger Flammable liquids]

H315 (34.1%): Causes skin irritation [Warning Skin corrosion/irritation]

H318 (49.4%): Causes serious eye damage [Danger Serious eye damage/eye irritation]

H319 (50.6%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]

H335 (33.5%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P305+P354+P338, P317, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 170 reports by companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Section 9. Physical and Chemical Properties

Colorless liquid; [Alfa Aesar MSDS]

Other Classes -> Esters, Other

EU Flavoring substances

Fragrance substance (Methyl crotonate) -> IFRA amendment 40

Section 11. Toxicological Information

Skin Sensitizer - An agent that can induce an allergic reaction in the skin.

LC (rat) > 19,000 ppm/6hr

Source: PubChem CID 638132 (NIH/NLM, public domain). Retrieved from PubChem, a public-domain chemistry database maintained by the U.S. National Library of Medicine. Last updated: 2026-08-02 09:35:34.
Disclaimer: This information is compiled for reference only and does not replace the manufacturer's official Safety Data Sheet. Always consult the supplier's SDS before handling any chemical.