neon

H280 (62.6%): Contains gas under pressure; may explode if heated [Warning Gases under pressure]

H281 (37.4%): Contains refrigerated gas; may cause cryogenic burns or injury [Warning Gases under pressure]

P282, P336+P317, P403, and P410+P403 (click each P-code to see the statement)

Aggregated GHS information provided per 430 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Fresh air, rest. Artificial respiration may be needed. Seek medical attention if you feel unwell.

Excerpt from ERG Guide 120 [Gases - Inert (Including Refrigerated Liquids)]:

Refer to the "General First Aid" section. Specific First Aid: Clothing frozen to the skin should be thawed before being removed. In case of contact with liquefied gas, only medical personnel should attempt thawing frosted parts. (ERG, 2024)

General First Aid:

· Call 911 or emergency medical service.

· Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and avoid contamination.

· Move victim to fresh air if it can be done safely.

· Administer oxygen if breathing is difficult.

· If victim is not breathing:

-- DO NOT perform mouth-to-mouth resuscitation; the victim may have ingested or inhaled the substance.

-- If equipped and pulse detected, wash face and mouth, then give artificial respiration using a proper respiratory medical device (bag-valve mask, pocket mask equipped with a one-way valve or other device).

-- If no pulse detected or no respiratory medical device available, provide continuous compressions. Conduct a pulse check every two minutes or monitor for any signs of spontaneous respirations.

· Remove and isolate contaminated clothing and shoes.

· For minor skin contact, avoid spreading material on unaffected skin.

· In case of contact with substance, remove immediately by flushing skin or eyes with running water for at least 20 minutes.

· For severe burns, immediate medical attention is required.

· Effects of exposure (inhalation, ingestion, or skin contact) to substance may be delayed.

· Keep victim calm and warm.

· Keep victim under observation.

· For further assistance, contact your local Poison Control Center.

· Note: Basic Life Support (BLS) and Advanced Life Support (ALS) should be done by trained professionals.

Specific First Aid:

· Clothing frozen to the skin should be thawed before being removed.

· In case of contact with liquefied gas, only medical personnel should attempt thawing frosted parts.

Excerpt from ERG Guide 120 [Gases - Inert (Including Refrigerated Liquids)]:

Use extinguishing agent suitable for type of surrounding fire. If it can be done safely, move undamaged containers away from the area around the fire. Damaged cylinders should be handled only by specialists.

FIRE INVOLVING TANKS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Do not direct water at source of leak or safety devices; icing may occur. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks in direct contact with flames. (ERG, 2024)

In case of fire in the surroundings, use appropriate extinguishing media. In case of fire: keep cylinder cool by spraying with water.

If material involved in fire: Extinguish fire using agent suitable for type of surrounding fire. Material itself does not burn or burns with difficulty. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible. /Neon, compressed; Neon, refrigerated liquid/

Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special protective equipment for fire-fighters: Wear self contained breathing apparatus for fire fighting if necessary.

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· Keep unauthorized personnel away.

· Stay upwind, uphill and/or upstream.

· Many gases are heavier than air and will spread along the ground and collect in low or confined areas (sewers, basements, tanks, etc.).

· Ventilate closed spaces before entering, but only if properly trained and equipped.

· Do not touch or walk through spilled material.

· Stop leak if you can do it without risk.

· Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material.

· Do not direct water at spill or source of leak.

· If possible, turn leaking containers so that gas escapes rather than liquid.

· Prevent entry into waterways, sewers, basements or confined areas.

· Allow substance to evaporate.

· Ventilate the area.

CAUTION: When in contact with refrigerated/cryogenic liquids, many materials become brittle and are likely to break without warning.

Excerpt from ERG Guide 120 [Gases - Inert (Including Refrigerated Liquids)]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area for at least 100 meters (330 feet) in all directions.

LARGE SPILL: Consider initial downwind evacuation for at least 100 meters (330 feet).

FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024)

Immediate precautionary measure

· Isolate spill or leak area for at least 100 meters (330 feet) in all directions.

Large Spill

· Consider initial downwind evacuation for at least 100 meters (330 feet).

· If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

Personal protection: self-contained breathing apparatus. Ventilation.

Personal precautions: Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Environmental precautions: Do not let product enter drains. Methods and materials for containment and cleaning up: Clean up promptly by sweeping or vacuum.

SRP: The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational harm/injury/toxicity or environmental contamination. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality; potential migration in soil or water; effects on animal and plant life; and conformance with environmental and public health regulations.

If material not involved in fire: Attempt to stop leak it without undue personnel hazard. /Neon, compressed; Neon, refrigerated liquid/

Personnel protection: Avoid breathing vapors. Keep upwind. Do not handle broken packages unless wearing appropriate personal protective equipment. /Neon, compressed; Neon, refrigerated liquid/

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

Excerpt from ERG Guide 120 [Gases - Inert (Including Refrigerated Liquids)]:

Do not touch or walk through spilled material. Stop leak if you can do it without risk. Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. Do not direct water at spill or source of leak. If possible, turn leaking containers so that gas escapes rather than liquid. Prevent entry into waterways, sewers, basements or confined areas. Allow substance to evaporate. Ventilate the area. CAUTION: When in contact with refrigerated/cryogenic liquids, many materials become brittle and are likely to break without warning. (ERG, 2024)

Fireproof if in building. Keep in a well-ventilated room.

Keep container tightly closed in a dry and well-ventilated place. Contents under pressure.

· Wear positive pressure self-contained breathing apparatus (SCBA).

· Structural firefighters' protective clothing provides thermal protection but only limited chemical protection.

· Always wear thermal protective clothing when handling refrigerated/cryogenic liquids or solids.

65000 [ppm]

230000 [ppm]

400000 [ppm]

Simple asphyxiant. /A simple asphyxiant may not be assigned a TLV because the limiting factor is the available oxygen./

· Use extinguishing agent suitable for type of surrounding fire.

· If it can be done safely, move undamaged containers away from the area around the fire.

· Damaged cylinders should be handled only by specialists.

Fire Involving Tanks

· Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles.

· Cool containers with flooding quantities of water until well after fire is out.

· Do not direct water at source of leak or safety devices; icing may occur.

· Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.

· ALWAYS stay away from tanks in direct contact with flames.

On loss of containment this substance can cause suffocation by lowering the oxygen content of the air in confined areas.

Asphyxiation.

Half-life: 17.34 seconds. Decay Mode: Electron Capture /Neon-19/

Excerpt from ERG Guide 120 [Gases - Inert (Including Refrigerated Liquids)]:

Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing provides thermal protection but only limited chemical protection. Always wear thermal protective clothing when handling refrigerated/cryogenic liquids or solids. (ERG, 2024)

Personnel protection: Wear appropriate chemical protective gloves, boots, and goggles. /Neon, compressed; Neon, refrigerated liquid/

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Use ventilation.

Neon appears as a colorless odorless noncombustible gas. Chemically inert. The vapors are lighter than air. Nontoxic, but can act as a simple asphyxiant. Exposure of the container to prolonged heat or fire may cause it to rupture violently and rocket. Principal use is to fill lamp bulbs and tubes.

Neon, refrigerated liquid (cryogenic liquid) appears as a colorless, odorless, extremely cold liquid. Rapidly evolves into neon gas. Nontoxic and chemically inert. May act as an asphyxiate by displacement of oxygen. Contact with the liquid may cause frostbite. Exposure of container to prolonged heat or fire may cause violent rupture and rocket.

A colorless odorless noncombustible gas; [CAMEO]

COLOURLESS ODOURLESS COMPRESSED GAS.

Colorless gas

Monoatomic, inert ... Does not condense at the temperature of liquid air; solid at the temperature of liquid hydrogen; the solid form exists as face-centered cubic crystals at normal pressure

Odorless

Tasteless

-246.053 °C

-246.1 °C

-245.9 °C @760 [mm Hg]

-248.609 °C triple point (43 kPa)

-248.7 °C

-248.67 °C

Negligible

Solubility of gas in water (20 °C): 10.5 cu cm/kg water

Solubility in water: very poor

0.825 g/L

GAS: density: 0.899994 kg/cu m at 0 °C (101.3 kPa): 9.552 kg/cu m (normal BP)

SOLID: normal density: 1444 kg/cu m (triple point); Heat of vaporization: 2.139 kJ/mol (triple point); Heat of fusion: 0.335 kJ/mol (triple point)

1.204 @ BP

0.6964 (Air = 1)

Relative vapor density (air = 1): 0.69

log Kow = 0.28

Natural neon is a mixture of three stable isotopes. Fourteen other unstable isotopes are known.

Does not form compounds, but ionizes in electric discharge tubes

Liquefies at -245.92 °C

Triple point temperature: 24.562 K, pressure 43.47 kPa

For more Other Experimental Properties (Complete) data for Neon, Elemental (8 total), please visit the HSDB record page.

LIQUID: normal BP: -246.08 °C; density: 1207 kg/cu m at 0 °C (normal bp): 1247 kg/cu m (triple point); Heat of vaporization: 1.741 kJ/mol (normal BP)

thermal expansion coefficient

Auger electron spectroscopy

dielectric constant

satellite line

crystal structure

fusion temperature

dielectricity

diffusion

piezooptic effect

enthalpy

No rapid reaction with air. No rapid reaction with water.

Not Chemically Reactive

These substances undergo no chemical reactions under any known circumstances. They are nonflammable, noncombustible and nontoxic. They can asphyxiate.

These substances undergo no chemical reactions under any known circumstances. They are nonflammable, noncombustible and nontoxic. They can asphyxiate. Contact of very cold liquefied gas with water may result in vigorous or violent boiling of the product and extremely rapid vaporization due to the large temperature differences involved. If the water is hot, there is the possibility that a liquid "superheat" explosion may occur. Pressures may build to dangerous levels if liquid gas contacts water in a closed container [Handling Chemicals Safely 1980].

Dizziness. Lethargy. Headache. Suffocation.

Other Poison - Simple Asphyxiant

...The anesthetic properties of helium and neon at hyperbaric pressures /were assessed/ by testing their capacity to decrease anesthetic requirement for desflurane using electrical stimulation of the tail as the anesthetic endpoint (ie, the minimum alveolar anesthetic concentration [MAC]) in rats. Partial pressures of helium or neon near those predicted to produce anesthesia by the Meyer-Overton hypothesis (approximately 80-90 atm), tended to increase desflurane MAC, and these partial pressures of helium and neon produced convulsions when administered alone. ... It has been thought that the high pressures of helium and neon that might be needed to produce anesthesia, antagonize their anesthetic properties (pressure reversal of anesthesia). /The authors/ propose an alternative explanation: like other compounds with a low affinity to water, helium and neon are intrinsically without anesthetic effect.

Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Simple asphyxiants and related compounds/

Basic treatment: Establish a patent airway (oropharyngeal or nasopharyngeal airway, if needed). Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Anticipate seizures and treat if necessary ... . Use rapid rewarming techniques if frostbite occurs ... . /Simple asphyxiants and related compounds/

Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious or is in severe respiratory distress. Monitor cardiac rhythm and treat arrhythmias if necessary ... . Start IV administration of D5W /SRP: "To keep open", minimal flow rate/. Treat seizures with diazepam or lorazepam ... . /Simple asphyxiants and related compounds/

/SIGNS AND SYMPTOMS/ Contact with the liquid can cause frostbite. /Neon, refrigerated liquid/

/OTHER TOXICITY INFORMATION/ Neon is among the number of gases and vapors that, when present in high concentrations in air, act primarily as simple asphyxiants without other significant physiologic effects.

Neon is a rare gaseous element present in the atmosphere to the extent of 1 part in 65,000 parts of air.

NIOSH (NOES Survey 1981-1983) has statistically estimated that 1,416 workers (125 of these were female) were potentially exposed to neon in the US(1).

Neon is a rare gaseous element present in the atmosphere to the extent of 1 part in 65,000 parts of air.

NIOSH (NOES Survey 1981-1983) has statistically estimated that 1,416 workers (125 of these were female) were potentially exposed to neon in the US(1).

SRP: The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational harm/injury/toxicity or environmental contamination. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality; potential migration in soil or water; effects on animal and plant life; and conformance with environmental and public health regulations.

/GUIDE 120: GASES - INERT (INCLUDING REFRIGERATED LIQUIDS)/ Health: Vapors may cause dizziness or asphyxiation without warning. Vapors from liquefied gas are initially heavier than air and spread along ground. Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. /Neon, refrigerated liquid (cryogenic liquid)/

/GUIDE 120: GASES - INERT (INCLUDING REFRIGERATED LIQUIDS)/ Fire or Explosion: Non-flammable gases. Containers may explode when heated. Ruptured cylinders may rocket. /Neon, refrigerated liquid (cryogenic liquid)/

/GUIDE 120: GASES - INERT (INCLUDING REFRIGERATED LIQUIDS)/ Public Safety: CALL Emergency Response Telephone Number ... As an immediate precautionary measure, isolate spill or leak area for at least 100 meters (330 feet) in all directions. Keep unauthorized personnel away. Stay upwind. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Keep out of low areas. Ventilate closed spaces before entering. /Neon, refrigerated liquid (cryogenic liquid)/

/GUIDE 120: GASES - INERT (INCLUDING REFRIGERATED LIQUIDS)/ Protective Clothing: Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing will only provide limited protection. Always wear thermal protective clothing when handling refrigerated/cryogenic liquids or solids. /Neon, refrigerated liquid (cryogenic liquid)/

For more DOT Emergency Guidelines (Complete) data for Neon, Elemental (16 total), please visit the HSDB record page.

Non-Flammable Gas

UN Hazard Class: 2.2