Tin tetrachloride

H314: Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

H412: Harmful to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]

P260, P264, P273, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P405, and P501 (click each P-code to see the statement)

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

H318 (30%): Causes serious eye damage [Danger Serious eye damage/eye irritation]

H335 (31.2%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

H412 (99.6%): Harmful to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]

P260, P261, P264, P264+P265, P271, P273, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P321, P363, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 237 reports by companies from 17 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

H318: Causes serious eye damage [Danger Serious eye damage/eye irritation]

H330: Fatal if inhaled [Danger Acute toxicity, inhalation]

H335: May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

H372: Causes damage to organs through prolonged or repeated exposure [Danger Specific target organ toxicity, repeated exposure]

H401: Toxic to aquatic life [Hazardous to the aquatic environment, acute hazard]

P260, P261, P264, P264+P265, P270, P271, P273, P280, P284, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P320, P321, P363, P403+P233, P405, and P501 (click each P-code to see the statement)

H290: May be corrosive to metals [Warning Corrosive to Metals]

P234, P260, P261, P264, P264+P265, P270, P271, P280, P284, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P320, P321, P363, P390, P403+P233, P405, P406, and P501 (click each P-code to see the statement)

Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention.

Rinse skin with plenty of water or shower. Refer for medical attention .

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Do NOT induce vomiting. Refer for medical attention .

Excerpt from ERG Guide 137 [Substances - Water-Reactive - Corrosive]:

Refer to the "General First Aid" section. Specific First Aid: For corrosives, in case of contact, immediately flush skin or eyes with running water for at least 30 minutes. Additional flushing may be required. Removal of solidified molten material from skin requires medical assistance. (ERG, 2024)

General First Aid:

· Call 911 or emergency medical service.

· Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and avoid contamination.

· Move victim to fresh air if it can be done safely.

· Administer oxygen if breathing is difficult.

· If victim is not breathing:

-- DO NOT perform mouth-to-mouth resuscitation; the victim may have ingested or inhaled the substance.

-- If equipped and pulse detected, wash face and mouth, then give artificial respiration using a proper respiratory medical device (bag-valve mask, pocket mask equipped with a one-way valve or other device).

-- If no pulse detected or no respiratory medical device available, provide continuous compressions. Conduct a pulse check every two minutes or monitor for any signs of spontaneous respirations.

· Remove and isolate contaminated clothing and shoes.

· For minor skin contact, avoid spreading material on unaffected skin.

· In case of contact with substance, remove immediately by flushing skin or eyes with running water for at least 20 minutes.

· For severe burns, immediate medical attention is required.

· Effects of exposure (inhalation, ingestion, or skin contact) to substance may be delayed.

· Keep victim calm and warm.

· Keep victim under observation.

· For further assistance, contact your local Poison Control Center.

· Note: Basic Life Support (BLS) and Advanced Life Support (ALS) should be done by trained professionals.

Specific First Aid:

· For corrosives, in case of contact, immediately flush skin or eyes with running water for at least 30 minutes. Additional flushing may be required.

· Removal of solidified molten material from skin requires medical assistance.

In Canada, an Emergency Response Assistance Plan (ERAP) may be required for this product. Please consult the shipping paper and/or the "ERAP" section.

Excerpt from ERG Guide 137 [Substances - Water-Reactive - Corrosive]:

When material is not involved in fire, do not use water on material itself.

SMALL FIRE: Dry chemical or CO2. If it can be done safely, move undamaged containers away from the area around the fire.

LARGE FIRE: Flood fire area with large quantities of water, while knocking down vapors with water fog. If insufficient water supply, responders should withdraw.

FIRE INVOLVING TANKS, RAIL TANK CARS OR HIGHWAY TANKS: Cool containers with flooding quantities of water until well after fire is out. Do not get water inside containers. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks in direct contact with flames. (ERG, 2024)

NO hydrous agents. In case of fire in the surroundings, use appropriate extinguishing media.

Use appropriate extinguishing agents on nearby combustible fires. Do not use water-based extinguishers on fires where this material has been released. use water spray to keep fire-exposed containers cool. Visibility can be reduced by the solid tin oxide fumes produced when reacted with moisture.

If material involved in fire: Use dry chemical, dry sand, or carbon dioxide. Do not use water on material itself. If large quantities of combustibles are involved, use water in flooding quantities as spray & fog. Use water to knock down vapors. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible.

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· Keep unauthorized personnel away.

· Stay upwind, uphill and/or upstream.

· Ventilate closed spaces before entering, but only if properly trained and equipped.

· Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.

· Stop leak if you can do it without risk.

· Use water spray to reduce vapors; do not put water directly on leak, spill area or inside container.

· Keep combustibles (wood, paper, oil, etc.) away from spilled material.

Small Spill

· Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain.

· Use clean, non-sparking tools to collect material and place it into loosely covered plastic containers for later disposal.

· Prevent entry into waterways, sewers, basements or confined areas.

Excerpt from ERG Guide 137 [Substances - Water-Reactive - Corrosive]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.

FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024)

Immediate precautionary measure

· Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

· For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.

· For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind direction, as necessary.

· If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

Evacuate danger area! Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Ventilation. Cautiously neutralize spilled liquid with soda ash or lime. Then store and dispose of according to local regulations.

Cover ... spills with sufficient amount of sodium bicarbonate. Remove the mixture in a container such as a fiber drum, plastic bag or carton box for easy disposal. ...

If material not involved in fire: ... Neutralize spilled material with crushed limestone, soda ash, or lime.

If tin, stannous chloride, stannic chloride, stannous sulfate, or potassium stannate are spilled or leaked, the following steps should be taken: 1. Ventilate area of spill or leak. 2. Collect spilled or leaked material in the most convenient and safe manner for reclamation or for disposal. ... Liquid containing inorganic tin compounds should be absorbed in vermiculite, dry sand, earth, or a similar material.

Use water spray to cool and disperse vapors, protect personnel, and carefully dilute spills to form nonreactive mixtures.

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

SRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.

Nonimpervious clothing which becomes contaminated with stannic chloride ... should be removed immediately & not reworn until the contaminant is removed from the clothing.

Clothing contaminated with stannous chloride /or/ stannic chloride ... should be placed in closed containers for storage until it can be discarded or until provision is made for the removal of contaminant from the clothing. If the clothing is to be laundered or otherwise cleaned to remove the contaminant, the person performing the operation should be informed of contaminant's hazardous properties.

Where there is possibility of exposure ... liquid stannic chloride, facilities for quick drenching of the body should be provided ... for emergency use. ... Where there is any possibility that employees' eyes may be exposed to liquid stannic chloride ... an eye wash fountain should be provided within the immediate work area for emergency use.

For more Preventive Measures (Complete) data for STANNIC CHLORIDE (9 total), please visit the HSDB record page.

Excerpt from ERG Guide 137 [Substances - Water-Reactive - Corrosive]:

Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Use water spray to reduce vapors; do not put water directly on leak, spill area or inside container. Keep combustibles (wood, paper, oil, etc.) away from spilled material.

SMALL SPILL: Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain. Use clean, non-sparking tools to collect material and place it into loosely covered plastic containers for later disposal. Prevent entry into waterways, sewers, basements or confined areas. (ERG, 2024)

Separated from food and feedstuffs. Dry. Well closed. Keep in a well-ventilated room.

Store in a cool, dry, well-ventilated location. Outside or detached storage is preferred.

KEEP WELL STOPPERED

· Wear positive pressure self-contained breathing apparatus (SCBA).

· Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE.

· Structural firefighters' protective clothing provides thermal protection but only limited chemical protection.

0.16 [mg/m3]

1.8 [mg/m3]

11 [mg/m3]

2.0 [mg/m3], as Sn

8 hr Time Weighted Avg (TWA): 2 mg/cu m. /Tin, as Sn, oxide & inorganic cmpd, except tin hydride/

Excursion Limit Recommendation: Excursions in worker exposure levels may exceed 3 times the TLV-TWA for no more than a total of 30 minutes during a work day, and under no circumstances should they exceed 5 times the TLV-TWA, provided that the TLV-TWA is not exceeded. /Tin, as Sn, oxide & inorganic cmpd, except tin hydride/

· When material is not involved in fire, do not use water on material itself.

Small Fire

· Dry chemical or CO2.

· If it can be done safely, move undamaged containers away from the area around the fire.

Large Fire

· Flood fire area with large quantities of water, while knocking down vapors with water fog. If insufficient water supply, responders should withdraw.

Fire Involving Tanks, Rail Tank Cars or Highway Tanks

· Cool containers with flooding quantities of water until well after fire is out.

· Do not get water inside containers.

· Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.

· ALWAYS stay away from tanks in direct contact with flames.

A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20 °C.

The substance is corrosive to the eyes, skin and respiratory tract. Corrosive on ingestion.

Excerpt from ERG Guide 137 [Substances - Water-Reactive - Corrosive]:

Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE. Structural firefighters' protective clothing provides thermal protection but only limited chemical protection. (ERG, 2024)

Employees should be provided with & required to use impervious clothing, gloves, face shields (eight inch minimum), & other appropriate protective clothing necessary to prevent any possibility of skin contact with liq stannic chloride.

Employees should be provided with & required to use dust & splash proof goggles where there is any possibility of liquid stannic chloride ... contacting the eyes.

Wear appropriate chemical protective ... boots. ...

STRICT HYGIENE! IN ALL CASES CONSULT A DOCTOR!

Use ventilation, local exhaust or breathing protection.

Protective gloves. Protective clothing.

Wear safety goggles, face shield or eye protection in combination with breathing protection.

Do not eat, drink, or smoke during work.

Stannic chloride, anhydrous is a colorless fuming liquid with a pungent odor. It is soluble in cold water and decomposed by hot water to form hydrochloric acid with the evolution of heat. It is corrosive to metals and tissue.

Fuming liquid; [Merck Index] Colorless or slightly yellow fuming liquid; [ICSC] Colorless or light yellow liquid with an acrid odor; [MSDSonline]

COLOURLESS OR SLIGHTLY YELLOW FUMING LIQUID WITH PUNGENT ODOUR.

Colorless fuming liquid

114.15 °C

114.1 °C @760 [mm Hg]

White or slightly yellow crystals or fused small lumps; slight hydrochloric acid odor; very sol in water; sol in alcohol /stannic chloride pentahydrate/

Soluble in acetone, ethanol, gasoline, benzene, carbon tetrachloride, toluene, kerosene, methanol

Sol in cold water (decomposes in hot water), carbon disulfide

Soluble in ethanol, carbon tetrachloride, benzene and acetone.

Solubility in water: reaction

2.34 g/cu cm

Relative density (water = 1): 2.26

2.232 @25 °C

9 (air= 1)

Relative vapor density (air = 1): 9.0

18.0 [mmHg]

18 MM HG AT 20 °C

Vapor pressure, kPa at 20 °C: 2.4

10 [mm Hg] @10 °C

When heated to decomposition it emits toxic fumes of /chloride/.

Corrosive to metals

Will attack some forms of plastics, rubber, & coatings.

INDEX OF REFRACTION: 1.512

MP: approx 56 deg (decomposes); density: 2.04 g/cu cm /Stannic chloride, pentahydrate/

Monoclinic crystals, /Stannic chloride, pentahydrate/

Deliquescent solid/Stannic chloride, pentahydrate/

Opaque; bp: stable 56 to 83 °C; sol in cold water /Stannic chloride, tetrahydrate/

Colorless monoclinic crystals; mp: 80 °C; bp: stable 64 to 83 °C; sol in cold water /Stannic chloride, trihydrate/

Heat of fusion: 9.20 kJ/mol

Dielectric constant: 2.97 @ 20 °C

Reacts with water.

Metals -> Metals, Inorganic Compounds

Corrosives

Reactive agents - 1st degree

Use unspecified -> FDA Substance added to food

Fumes in moist air. Reacts with water to form Hydrochloric Acid in dense white fumes [Merck 11th ed. 1989].

Acids, Strong Non-oxidizing

Water-Reactive

Air-Reactive

STANNIC CHLORIDE readily hydrolyzes to form hydrochloric acid in aqueous solution or moist air. Combination of stannic chloride with turpentine is strongly exothermic, and may lead to ignition [Mellor, 1941, Vol. 7, 446].

STANNIC CHLORIDE REACTS WITH TURPENTINE, PRODUCING HEAT AND SOMETIMES FLAME.

A MIXTURE OF POTASSIUM OR SODIUM AND STANNIC CHLORIDE PRODUCES A STRONG EXPLOSION ON IMPACT.

Violent reaction with ... ethylene oxide. ...

Ethyl, isopropyl, butyl, benzyl, & triphenylmethyl nitrates in contact with ... tin(IV) chloride ... interact violently ... with gas evolution.

For more Hazardous Reactivities and Incompatibilities (Complete) data for STANNIC CHLORIDE (6 total), please visit the HSDB record page.

Inorganic and organic tin compounds are weak inhibitors of alcohol dehydrogenase. (A183)

No indication of carcinogenicity to humans (not listed by IARC).

Ingestion of large amounts of inorganic tin compounds can cause stomachache, anemia, and liver and kidney problems. (L307, L308)

Oral (L308) ; inhalation (L308) ; dermal (L308)

Cough. Sore throat. Burning sensation. Laboured breathing. Shortness of breath. Wheezing.

Redness. Pain. Skin burns.

Redness. Pain. Severe deep burns.

Abdominal pain. Burning sensation. Shock or collapse.

Inorganic or organic tin compounds placed on the skin or in the eyes can produce skin and eye irritation. (L308)

Dermatotoxin - Skin burns.

Toxic Pneumonitis - Inflammation of the lungs induced by inhalation of metal fumes or toxic gases and vapors.

LC50 (rat) = 2,300 mg/m3/10min

LD50: 46 mg/kg (Intraperitoneal, Mouse) (T57)

LC50: 2300 mg/m3 over 10 minutes (Inhalation, Rat) (T14)

LD50 Mouse intraperitoneal 46 mg/kg

LC50 Rat inhalation 2300 mg/cu m/10 min

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

... Prolonged contact with the skin causes burns ... .

Concern about upper respiratory tract irritation and other symptoms among workers at a glass bottle manufacturing plant led to an epidemiologic and an industrial hygiene survey. Questionnaire responses from 35 hot end and 53 cold end workers indicated that the incidence of wheezing, chest pain, dyspnea on exertion, and cough was significantly elevated among hot end workers. Among smokers and nonsmokers, hot end workers reported higher, but not significantly higher rates of wheezing and chest pain. Among smokers, hot end workers reported significantly higher rates of dyspnea on exertion and cough than did cold end workers. Reported exposure to stannic chloride solution likely caused these symptoms. The industrial hygiene survey, conducted when stannic chloride use had ben reduced, cleaning had been done and ventilation improved, focused on measuring air contaminants that might have caused symptoms. Levels of HCl which apparently was formed by the combination of stannic chloride and water in the presence of heat, were elevated. The finding of increased prevalence of respiratory symptoms among hot end workers was consistent with this exposure. Recommendations were made to reduce hazardous exposures at this plant. Individuals responsible for occupational health should be aware that relatively benign substances, such as stannic chloride and water, can combine spontaneously to form hazardous substances.

Stannic chloride is a fuming caustic liquid, highly irritating to the eyes and mucous membranes. The irritating presumably is attributable t o the hydrochloric acid which is generated when stannic chloride reacts with water.

INHALATION EXPOSURE FOR 10 MIN TO TIN TETRACHLORIDE AT CONCN OF 3 MG/CU M WAS SAID TO BE WELL TOLERATED BY GUINEA PIGS. EVEN REPEATED EXPOSURES TO THIS CONCN WAS CLAIMED TO BE TOLERATED.

Microbial communities in water from Baltimore Harbor (Maryland, USA) and from the mainstem of Chesapeake Bay were examined for sensitivity to mercury chloride, monomethyl mercury, stannic chloride, and tributyltin chloride. Acute toxicity was determined by measuring the effects on (3)H-thymidine incorporation, (14)C-glutamate incorporation and respiration, and viability as compared with those of controls. Minimum inhibitory concn were low for all metals except stannic chloride (5 mg/l). The Chesapeake Bay community appeared to be slightly more sensitive to metal stress than the Baltimore Harbor community, but this was not true for all treatments or assays. For culturable bacteria, the opposite result was found. Thymidine incorporation and glutamate metabolism were much more sensitive indicators of metal toxicity than was viability. The use of thymidine incorporation method for ecotoxicology studies was at least equal in sensitivity to metabolic measurements and likely measures the effects on the greater portion of the natural community.

Twenty one different metal chlorides have been tested for mutagenicity in the presence of 9-aminoacridine in strains of Salmonella typhimurium. Stannic chloride was not mutagenic alone, exhibited mutagenicity when combined with 9-aminoacridine in strains TA1537 and TA2637.

The substance is harmful to aquatic organisms.

The substance is harmful to aquatic organisms.

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

/GUIDE 137: SUBSTANCES - WATER-REACTIVE - CORROSIVE/ Health: CORROSIVE and/or TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns, or death. Fire will produce irritating, corrosive and/or toxic gases. Reaction with water may generate much heat which will increase the concentration of fumes in the air. Contact with molten substance may cause severe burns to skin and eyes. Runoff from fire control or dilution water may cause pollution. /Stannic chloride, anhydrous/

/GUIDE 137: SUBSTANCES - WATER-REACTIVE - CORROSIVE/ Fire or Explosion: ... Some of these materials may burn, but none ignite readily. May ignite combustibles (wood, paper, oil, clothing, etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases. Flammable/toxic gases may accumulate in confined areas (basement, tanks, hopper/tank cars etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water. Substance may be transported in a molten form. /Stannic chloride, anhydrous/

/GUIDE 137: SUBSTANCES - WATER-REACTIVE - CORROSIVE/ Public Safety: CALL Emergency Response Telephone Number ... . As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75) feet for solids. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate enclosed areas. /Stannic chloride, anhydrous/

/GUIDE 137: SUBSTANCES - WATER-REACTIVE - CORROSIVE/ Protective Clothing: Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. /Stannic chloride, anhydrous/

For more DOT Emergency Guidelines (Complete) data for STANNIC CHLORIDE (16 total), please visit the HSDB record page.

UN 1827; Stannic chloride, anhydrous

IMO 8.0; Stannic chloride, anhydrous and pentahydrate

UN 2440; Stannic chloride pentahydrate

49 999 41; Tin chloride, fuming

49 323 83; Tin tetrachloride, anhydrous

No person may /transport,/ offer or accept a hazardous material for transportation in commerce unless that person is registered in conformance ... and the hazardous material is properly classed, described, packaged, marked, labeled, and in condition for shipment as required or authorized by ... /the hazardous materials regulations (49 CFR 171-177)./

The International Air Transport Association (IATA) Dangerous Goods Regulations are published by the IATA Dangerous Goods Board pursuant to IATA Resolutions 618 and 619 and constitute a manual of industry carrier regulations to be followed by all IATA Member airlines when transporting hazardous materials.

The International Maritime Dangerous Goods Code lays down basic principles for transporting hazardous chemicals. Detailed recommendations for individual substances and a number of recommendations for good practice are included in the classes dealing with such substances. A general index of technical names has also been compiled. This index should always be consulted when attempting to locate the appropriate procedures to be used when shipping any substance or article.

Corrosive

Airtight. Unbreakable packaging. Put breakable packaging into closed unbreakable container. Do not transport with food and feedstuffs.

Symbol: C; R: 34-52/53; S: (1/2)-7/8-26-45-61

UN Hazard Class: 8; UN Pack Group: II