English Safety Data Sheet Database 中文版 MSDS

Phosphorus trifluoride

CAS No. 7783-55-3 | PubChem CID 62665
Section 1. Identification
Chemical NamePhosphorus trifluoride CAS No.7783-55-3
Synonymsphosphorus fluor-ide; phophoroustrifluoride Chinese Name三氟化磷
Molecular FormulaF3P Molecular Weight87.968972
UN No.1955 Data SourcePubChem (NIH/NLM)
GHS Hazard Classification
Signal Word DANGER
Pictograms GHS04 · Compressed Gas GHS05 · Corrosive GHS06 · Acute Toxic GHS07 · Irritant GHS08 · Health Hazard
Hazard Statements H280H314H330H331H320H335H372
Precautionary Statements P260P261P264P271P280P284P301+P330+P331P302+P361+P354P304+P340P305+P354+P338P316P320P321P363P403+P233P405P410+P403P501P264+P265P270P305+P351+P338P319P337+P317

Section 2. Hazards Identification

H280 (96.8%): Contains gas under pressure; may explode if heated [Warning Gases under pressure]

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

H330 (100%): Fatal if inhaled [Danger Acute toxicity, inhalation]

H331 (95.2%): Toxic if inhaled [Danger Acute toxicity, inhalation]

P260, P261, P264, P271, P280, P284, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P320, P321, P363, P403+P233, P405, P410+P403, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 124 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Not Classified

H320: Causes eye irritation [Warning Serious eye damage/eye irritation]

H330: Fatal if inhaled [Danger Acute toxicity, inhalation]

H335: May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

H372: Causes damage to organs through prolonged or repeated exposure [Danger Specific target organ toxicity, repeated exposure]

P260, P261, P264, P264+P265, P270, P271, P284, P304+P340, P305+P351+P338, P316, P319, P320, P337+P317, P403+P233, P405, and P501 (click each P-code to see the statement)

Section 8. Exposure Controls / Personal Protection

1.0 [mg/m3], inhalable fraction, as F[German Research Foundation (DFG)]

0.13 [mg/m3]

1.4 [mg/m3]

8.6 [mg/m3]

2.5 [mg/m3], as F

Section 9. Physical and Chemical Properties

Colorless gas; [Merck Index]

-102 °C @760 [mm Hg]

31P nuclear magnetic resonance spectrum

Schoenflies notation

Centrifugal distortion

Chemical bond

Chemical shift

Crystal structure

Doubling constant

Excitation energy

Internuclear distance

Molecular structure

Point group

Rotational excitation cross section

Spin-spin coupling constant

Other Classes -> Fluorides, Inorganic

Section 11. Toxicological Information

Dermatotoxin - Skin burns.

Toxic Pneumonitis - Inflammation of the lungs induced by inhalation of metal fumes or toxic gases and vapors.

LCLo (mice) = 1,900 mg/m3/10min

Source: PubChem CID 62665 (NIH/NLM, public domain). Retrieved from PubChem, a public-domain chemistry database maintained by the U.S. National Library of Medicine. Last updated: 2026-08-02 09:54:35.
Disclaimer: This information is compiled for reference only and does not replace the manufacturer's official Safety Data Sheet. Always consult the supplier's SDS before handling any chemical.