| Section 1. Identification | |||
|---|---|---|---|
| Chemical Name | barium fluoride | CAS No. | 7787-32-8 |
| Synonyms | — | Chinese Name | 氟化钡 |
| Molecular Formula | BaF2 | Molecular Weight | 175.324 |
| UN No. | 1564 | Data Source | PubChem (NIH/NLM) |
| GHS Hazard Classification | |
|---|---|
| Signal Word | WARNING |
| Pictograms | GHS06 · Acute Toxic GHS07 · Irritant GHS08 · Health Hazard |
| Hazard Statements | H302H332H301H319H335H372H361 |
| Precautionary Statements | P261P264P270P271P301+P317P304+P340P317P330P501P260P264+P265P280P301+P316P305+P351+P338P319P321P337+P317P403+P233P405P203P318 |
| Contents | |||
|---|---|---|---|
| Section 2 | Hazards Identification | Section 8 | Exposure Controls / Personal Protection |
| Section 9 | Physical and Chemical Properties | Section 11 | Toxicological Information |
This chemical does not meet GHS hazard criteria for 0.4% (1 of 253) of reports.
H302 (92.1%): Harmful if swallowed [Warning Acute toxicity, oral]
H332 (99.2%): Harmful if inhaled [Warning Acute toxicity, inhalation]
P261, P264, P270, P271, P301+P317, P304+P340, P317, P330, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 253 reports by companies from 12 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Reported as not meeting GHS hazard criteria per 1 of 253 reports by companies.
There are 11 notifications provided by 252 of 253 reports by companies with hazard statement code(s).
Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.
H301: Toxic if swallowed [Danger Acute toxicity, oral]
H319: Causes serious eye irritation [Warning Serious eye damage/eye irritation]
H335: May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]
H372: Causes damage to organs through prolonged or repeated exposure [Danger Specific target organ toxicity, repeated exposure]
P260, P261, P264, P264+P265, P270, P271, P280, P301+P316, P304+P340, P305+P351+P338, P319, P321, P330, P337+P317, P403+P233, P405, and P501 (click each P-code to see the statement)
H361: Suspected of damaging fertility or the unborn child [Warning Reproductive toxicity]
P203, P260, P261, P264, P264+P265, P270, P271, P280, P301+P316, P304+P340, P305+P351+P338, P318, P319, P321, P330, P337+P317, P403+P233, P405, and P501 (click each P-code to see the statement)
Biological Exposure Indices (BEI) [ACGIH] - Fluorides in urine = 2 mg/L prior to shift or 3 mg/L at end of shift; (Repeated measurements recommended.)
0.5 [mg/m3], as Ba, inhalable fraction(soluble compds) [1 mg/m3, as F, inhalable fraction][German Research Foundation (DFG)]
5.1 [mg/m3]
16 [mg/m3]
99 [mg/m3]
0.5 [mg/m3], as Ba (2.5 mg/m3, as F)
50.0 [mg/m3], as Ba
Intermediate Oral: 0.2 mg/kg/day (L134)
Chronic Oral: 0.2 mg/kg/day (L134)
Large Crystals; Dry Powder
Transparent solid; Partially soluble in water (1.607 g/L at 20 deg C); [Merck Index] Colorless or white odorless lump; Slightly soluble in water; [Alfa Aesar MSDS]
2260 °C @760 [mm Hg]
4.893 @25 °C
thermal expansion coefficient
direct band gap
crystal structure
atomic force microscopy
dielectricity
diffusion
piezooptic effect
enthalpy
second-order nonlinear coefficient
Gibbs energy
molecular beam epitaxy
phase equilibrium
positional coordinate
temperature-composition section
space group
molecular structure
phase diagram
unit cell parameter
melting temperature
heat capacity
dissociation energy
third-order stiffness
crystallographic data
dielectric susceptibility
transition enthalpy
displacement parameter
doped material
band gap energy
structural transition temperature
heteroepitaxy
high frequency properties
crystallographic transition temperature
phase transition
piezooptic constant
elastic stiffness
self-diffusion
Barium is a competitive potassium channel antagonist that blocks the passive efflux of intracellular potassium, resulting in a shift of potassium from extracellular to intracellular compartments. The intracellular translocation of potassium results in a decreased resting membrane potential, making the muscle fibers electrically unexcitable and causing paralysis. Some of these barium's effects may also be due to barium induced neuromuscular blockade and membrane depolarization. (L214)
No indication of carcinogenicity to humans (not listed by IARC).
The health effects of the different barium compounds depend on how well the compound dissolves in water or the stomach contents. At low doses, barium acts as a muscle stimulant, while higher doses affect the nervous system, causing cardiac irregularities, tremors, weakness, anxiety, dyspnea, paralysisand possibly death. Barium may also cause gastrointestinal disturbances, damage the kidneys and cause decreases in body weight. (L214)
Oral (L214) ; inhalation (L214)
Ingesting excess barium may cause vomiting, abdominal cramps, diarrhea, difficulties in breathing, increased or decreased blood pressure, numbness around the face, and muscle weakness. High levels may result in changes in heart rhythm or paralysis and possibly death. (L214)
Nephrotoxin - The chemical is potentially toxic to the kidneys in the occupational setting.
ACGIH Carcinogen - Not Classifiable.
LD50: 250 mg/kg (Oral, Rat) (L273)
Intravenous infusion of potassium often relieves many of the symptoms of barium toxicity. (L214)