| Section 1. Identification | |||
|---|---|---|---|
| Chemical Name | Thallium bromide | CAS No. | 7789-40-4 |
| Synonyms | thallousbromide; thalliumbromide | Chinese Name | 溴化铊 |
| Molecular Formula | TlBr | Molecular Weight | 284.28 |
| UN No. | 1707 | Data Source | PubChem (NIH/NLM) |
| GHS Hazard Classification | |
|---|---|
| Signal Word | DANGER |
| Pictograms | GHS06 · Acute Toxic GHS08 · Health Hazard GHS09 · Environmental Hazard |
| Hazard Statements | H300H330H373H411 |
| Precautionary Statements | P260P264P270P271P273P284P301+P316P304+P340P316P319P320P321P330P391P403+P233P405P501 |
| Contents | |||
|---|---|---|---|
| Section 2 | Hazards Identification | Section 9 | Physical and Chemical Properties |
| Section 11 | Toxicological Information | ||
H300 (100%): Fatal if swallowed [Danger Acute toxicity, oral]
H330 (100%): Fatal if inhaled [Danger Acute toxicity, inhalation]
H373 (100%): May causes damage to organs through prolonged or repeated exposure [Warning Specific target organ toxicity, repeated exposure]
H411 (100%): Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]
P260, P264, P270, P271, P273, P284, P301+P316, P304+P340, P316, P319, P320, P321, P330, P391, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 47 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.
Not Classified
dielectric constant
pseudobinary system
crystal structure
Debye frequency
dielectricity
diffusion
piezooptic effect
enthalpy
effective mass
isothermal section
Gibbs energy
phase equilibrium
positional coordinate
temperature-composition section
electron conductivity
space group
enthalpy change
phase diagram
unit cell parameter
melting temperature
heat capacity
activation energy of resistivity
transition enthalpy
band gap energy
transport data
high frequency properties
phase transition
Grueneisen coefficient
piezooptic constant
elastic stiffness
charge carrier mobility
band structure
formation entropy
elastic coefficients
X-ray diffraction
magnetic susceptibility
ionic conductivity
atomic environment
quadrupole coupling
phase stability
Bromine is a powerful oxidizing agent and is able to release oxygen free radicals from the water in mucous membranes. These free radicals are also potent oxidizers and produce tissue damage. In additon, the formation of hydrobromic and bromic acids will result in secondary irritation. The bromide ion is also known to affect the central nervous system, causing bromism. This is believed to be a result of bromide ions substituting for chloride ions in the in actions of neurotransmitters and transport systems, thus affecting numerous synaptic processes. (L626, L627, A543)
No indication of carcinogenicity to humans (not listed by IARC).
Bromine vapour causes irritation and direct damage to the mucous membranes. Elemental bromine also burns the skin. The bromide ion is a central nervous system depressant and chronic exposure produces neuronal effects. This is called bromism and can result in central reactions reaching from somnolence to coma, cachexia, exicosis, loss of reflexes or pathologic reflexes, clonic seizures, tremor, ataxia, loss of neural sensitivity, paresis, papillar edema of the eyes, abnormal speech, cerebral edema, delirium, aggressiveness, and psychoses. (L625, L626, L627)
Oral (L626) ; inhalation (L626) ; dermal (L626)
Bromine vapour causes irritation and direct damage to the mucous membranes. Symptoms include lacrimation, rhinorrhoea, eye irritation with mucous secretions from the oropharyngeal and upper airways, coughing, dyspnoea, choking, wheezing, epistaxis, and headache. The bromide ion is a central nervous system depressant producing ataxia, slurred speech, tremor, nausea, vomiting, lethargy, dizziness, visual disturbances, unsteadiness, headaches, impaired memory and concentration, disorientation and hallucinations. This is called bromism. (L626, L627)
EYES: irrigate opened eyes for several minutes under running water.
INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice.
SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention.
INHALATION: supply fresh air. If required provide artificial respiration.